Dichlorido(N,N′-dibenzylideneethane-1,2-diamine-κ2
N,N′)[(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2
O,O′]titanium(IV)
2007 ◽
Vol 63
(11)
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pp. m2842-m2843
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Keyword(s):
The title compound, [TiCl2(C31H28O4)(C16H16N2)], is a titanium(IV) complex of the bidentate 2,2-dimethyl-α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanolate (TADDOLate) ligand containing also two chloride ions and a bidentate neutral N,N′-dibenzylideneethane-1,2-diamine ligand. The molecular structure has a distorted octahedral geometry around the titanium metal center. The Ti—N bond lengths of 2.246 (2) and 2.2476 (17) Å are long, indicating weak bonding between the titanium(IV) metal center and the imine N atoms. Though the two chloride ligands are trans to each other, they bend away from the Ti–TADDOLate bonds with a Cl—Ti—Cl angle of 163.96 (3)°.
2012 ◽
Vol 68
(8)
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pp. m1077-m1077
2015 ◽
Vol 71
(2)
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pp. 210-212
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2012 ◽
Vol 68
(6)
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pp. m829-m829
2012 ◽
Vol 68
(4)
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pp. m396-m397
2013 ◽
Vol 69
(2)
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pp. m89-m89
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2016 ◽
Vol 72
(1)
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pp. 17-20
2014 ◽
Vol 70
(5)
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pp. m170-m171
2012 ◽
Vol 68
(8)
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pp. m1058-m1059
2012 ◽
Vol 68
(6)
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pp. m830-m831
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