[Bis(pyridin-2-ylmethyl)amine-κ3
N,N′,N′′]tricarbonylrhenium(I) bromide hemihydrate
2012 ◽
Vol 68
(6)
◽
pp. m741-m742
Keyword(s):
The title compound, fac-[Re(C12H12N3)(CO)3]Br·0.5H2O, crystallizes with a cationic rhenium(I) unit, a bromide ion and half a water molecule, situated on a twofold rotation axis, in the asymmetric unit. The ReI atom is facially surrounded by three carbonyl ligands and a tridentate bis(pyridin-2-ylmethyl)amine ligand in a distorted octahedral environment. N—H...Br, O—H...Br, C—H...O and C—H...Br hydrogen bonds are present in the crystal structure and π–π stacking is also observed [centroid–centroid distances = 3.669 (1) Å and 4.054 (1) Å], giving rise to a three-dimentional network. The molecules pack in a head-to-head fashion along the ac plane.
2007 ◽
Vol 63
(3)
◽
pp. m892-m894
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2014 ◽
Vol 70
(11)
◽
pp. 396-399
Keyword(s):
2009 ◽
Vol 65
(6)
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pp. m658-m659
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2006 ◽
Vol 62
(5)
◽
pp. m980-m982
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2014 ◽
Vol 70
(9)
◽
pp. m324-m325
Keyword(s):
2016 ◽
Vol 72
(9)
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pp. 1242-1245
2020 ◽
Vol 76
(7)
◽
pp. 1139-1142
2014 ◽
Vol 70
(7)
◽
pp. m278-m279
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2015 ◽
Vol 71
(5)
◽
pp. 463-465
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Keyword(s):