scholarly journals Poly[μ5-{hydrogen bis[(E)-cinnamato]}-caesium]

2014 ◽  
Vol 70 (2) ◽  
pp. m43-m44 ◽  
Author(s):  
Graham Smith
Keyword(s):  
Hydrogen Bond ◽  
Coordination Polymer ◽  
Cinnamic Acid ◽  
Component Ratio ◽  
Two Dimensional ◽  
Polymeric Complex ◽  
Coordination Polyhedra ◽  
Rotation Axes ◽  
Structure Extension ◽  
Ligand Species

In the structure of the title polymeric complex, [Cs(C9H7O2)(C9H8O2)]n, a caesium salt oftrans-cinnamic acid, the Cs+ions of the two individual irregular CsO8coordination polyhedra lie on twofold rotation axes and are linked by four bridging carboxyl O-atom donors from two cinnamate ligand species. These two ligand components are interlinked through a delocalized H atom within a short O...H...O hydrogen bond. Structure extension gives a two-dimensional coordination polymer which lies parallel to (001). The structure was determined from a crystal twinned by non-merohedry, with a twin component ratio of approximately 1:1.

scholarly journals Two-dimensional coordination polymeric structures in caesium complexes with ring-substituted phenoxyacetic acids

2014 ◽  
Vol 70 (6) ◽  
pp. 606-612 ◽  
Author(s):  
Graham Smith ◽  
Daniel E. Lynch
Keyword(s):  
Acetic Acid ◽  
Water Molecule ◽  
Complex Iii ◽  
Phenoxyacetic Acid ◽  
Two Dimensional ◽  
Coordination Polyhedra ◽  
Bidentate Chelate ◽  
Phenoxyacetic Acids ◽  
Ligand Species ◽  
Polymeric Structures

The two-dimensional polymeric structures of the caesium complexes with the phenoxyacetic acid analogues (4-fluorophenoxy)acetic acid, (3-chloro-2-methylphenoxy)acetic acid and the herbicidally active (2,4-dichlorophenoxy)acetic acid (2,4-D), namely poly[[μ5-(4-fluorophenoxy)acetato][μ4-(4-fluorophenoxy)acetato]dicaesium], [Cs2(C8H6FO3)2]n, (I), poly[aqua[μ5-(3-chloro-2-methylphenoxy)acetato]caesium], [Cs(C9H8ClO3)(H2O)]n, (II), and poly[[μ7-(2,4-dichlorophenoxy)acetato][(2,4-dichlorphenoxy)acetic acid]caesium], [Cs(C8H5Cl2O3)(C8H6Cl2O3)]n, (III), are described. In (I), the Cs+cations of the two individual irregular coordination polyhedra in the asymmetric unit (one CsO7and the other CsO8) are linked by bridging carboxylate O-atom donors from the two ligand molecules, both of which are involved in bidentate chelateOcarboxy,Ophenoxyinteractions, while only one has a bidentate carboxylateO,O′-chelate interaction. Polymeric extension is achieved through a number of carboxylate O-atom bridges, with a minimum Cs...Cs separation of 4.3231 (9) Å, giving layers which lie parallel to (001). In hydrated complex (II), the irregular nine-coordination about the Cs+cation comprises a single monodentate water molecule, a bidentateOcarboxy,Ophenoxychelate interaction and six bridging carboxylate O-atom bonding interactions, giving a Cs...Cs separation of 4.2473 (3) Å. The water molecule forms intralayer hydrogen bonds within the two-dimensional layers, which lie parallel to (100). In complex (III), the irregular centrosymmetric CsO6Cl2coordination environment comprises two O-atom donors and two ring-substituted Cl-atom donors from two hydrogen bis[(2,4-dichlorophenoxy)acetate] ligand species in a bidentate chelate mode, and four O-atom donors from bridging carboxyl groups. The duplex ligand species lie across crystallographic inversion centres, linked through a short O—H...O hydrogen bond involving the single acid H atom. Structure extension gives layers which lie parallel to (001). The present set of structures of Cs salts of phenoxyacetic acids show previously demonstrated trends among the alkali metal salts of simple benzoic acids with no stereochemically favourable interactive substituent groups for formation of two-dimensional coordination polymers.

scholarly journals Poly[diethylammonium [tetra-μ2-cyanido-κ8 C:N-tricuprate(I)]], a two-dimensional network solid

IUCrData ◽  
2020 ◽  
Vol 5 (7) ◽  
Author(s):  
Peter W. R. Corfield ◽  
Thomas James Stavola
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
The Other ◽  
Two Dimensional ◽  
Rotation Axes ◽  
Compound C ◽  
Dimensional Network

The title compound, (C4H12N)[Cu3(CN)4] n , crystallizes as a CuCN network solid, with diethylammonium cations sandwiched between planar CuCN sheets comprised of trigonal planar and digonally coordinated CuI atoms bridged by linear CN groups to form 24-membered rings. The digonally coordinated CuI atoms and the diethylammonium cations lie on separate crystallographic twofold rotation axes. One of the two independent CN groups has a 50:50 disordered orientation, while the other has one orientation favored due to a N—H...NC hydrogen bond between the diethylammonium cation and the anionic CuCN framework. These hydrogen bonds link the sheets together into a three-dimensional network.

Crystal engineering using bisphenols and trisphenols. Complexes with 1,10-phenanthroline: hydrogen-bonded chains in adducts with 4,4′-biphenol (1/1) and 4,4′-sulfonyldiphenol (2/3), π–π stacked chains in the (1/2) adduct with 4,4′-thiodiphenol, and pairwise-interwoven nets in 1,1,1-tris(4-hydroxyphenyl)ethane–1,10-phenanthroline–methanol (1/1/1)

1999 ◽  
Vol 55 (4) ◽  
pp. 591-600 ◽  
Author(s):  
George Ferguson ◽  
Christopher Glidewell ◽  
Emma S. Lavender
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Crystal Engineering ◽  
Hydroxyl Group ◽  
Hydroxyl Groups ◽  
Two Dimensional ◽  
Rotation Axes ◽  
Molecular Components ◽  
Supramolecular Aggregation ◽  
Hydrogen Bonded

In 4,4′-biphenol–1,10-phenanthroline (1/1) [systematic name: 4,4′-biphenyldiol–1,10-phenanthroline (1/1)] the diphenol molecules lie across centres of inversion and the phenanthroline molecules lie across twofold rotation axes; the phenanthroline molecules act as chain-building units and the molecular components are linked into steeply zigzag C(16) chains parallel to [101] by means of O—H...N hydrogen bonds. In the structure of 4,4′-thiodiphenol–1,10-phenanthroline (1/2) the phenanthroline molecules act as chain-terminating units; the supramolecular aggregation is finite, with the bisphenol linked to each phenanthroline molecule by means of a single O—H...N hydrogen bond. π−π stacking interactions between the phenanthroline molecules in neighbouring hydrogen-bonded aggregates serve to link these aggregates into a continuous two-dimensional array. The phenanthroline molecules in 4,4′-sulfonyldiphenol–1,10-phenanthroline (2/3) play two roles: molecules in general positions act as chain-terminating units and are linked to the sulfonyldiphenol molecules by means of three-centre O—H...(N)2 hydrogen bonds, while those lying across twofold rotation axes act as chain builders and are linked to two different sulfonyldiphenol molecules by means of a two-centre O—H...N hydrogen bond in each case; the resulting U-shaped five-component aggregates are further linked by C—H...O=S hydrogen bonds into a C_3^3(17)[R_2^2(12)] `chain of rings' along [001]. In 1,1,1-tris(4-hydroxyphenyl)ethane–1,10-phenanthroline–methanol (1/1/1) [systematic name: 4,4′,4′′-ethylidynetriphenol–1,10-phenanthroline–methanol (1/1/1)] the phenanthroline molecules again act as chain-terminating units: the trisphenol molecules and the methanol molecules are linked by O—H...O hydrogen bonds into two-dimensional nets built from R_6^6(42) rings, and pairs of these nets are interwoven. The formation of each net utilizes two hydroxyl groups per trisphenol molecule as hydrogen-bond donors and the remaining hydroxyl group acts as donor to the phenanthroline molecule in a three-centre O—H...(N)2 hydrogenbond.

An Extended Network via Hydrogen Bond Linkage of the Linear Coordination Polymer [Cd(μ-dptz)(NO3)2]∞

2002 ◽  
Vol 2002 (5) ◽  
pp. 247-249 ◽  
Author(s):  
Miao Du ◽  
Xian-He Bu ◽  
Kumar Biradha ◽  
Mitsuhiko Shionoya
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Coordination Polymer ◽  
Two Dimensional ◽  
One Dimensional ◽  
Linear Coordination

The crystal structure of [Cd(μ-dptz)(NO3)2]∞ reveals a neutral one-dimensional coordination polymer exhibiting a two-dimensional architecture through inter-chain hydrogen-bonding.

The coordination polymer poly[[aqua(μ-oxalato)[1H-1,2,4-triazole-5(4H)-thione]cadmium(II)] monohydrate]

2014 ◽  
Vol 70 (2) ◽  
pp. 182-184 ◽  
Author(s):  
Qian Liang ◽  
Yu-Lin Wang ◽  
Yan Zhao ◽  
Gao-Juan Cao
Keyword(s):  
Hydrogen Bond ◽  
Coordination Polymer ◽  
Water Molecule ◽  
Layered Structure ◽  
Metal Organic Framework ◽  
Title Complex ◽  
Two Dimensional ◽  
Hydrogen Bond Interactions ◽  
Metal Organic ◽  
Organic Framework

The title complex, {[Cd(C2O4)(C2H3N3S)(H2O)]·H2O}n, has a two-dimensional metal–organic framework, with the CdIIcation coordinated by three oxalate ligands, a 1H-1,2,4-triazole-5(4H)-thione (H2trzS) ligand and a water molecule. The CdO6S and oxalate units form an extended two-dimensional layered structure, with the terminal H2trzS ligands bonded to the CdIIsites through the thione S atoms. Hydrogen-bond interactions exist between adjacent layers.

A spin-crossover phenomenon in a 2D heterometallic coordination polymer with [Pd(SCN)4]2− building blocks

2021 ◽  
Vol 50 (12) ◽  
pp. 4152-4158
Author(s):  
Kai-Ping Xie ◽  
Si-Guo Wu ◽  
Long-Fei Wang ◽  
Guo-Zhang Huang ◽  
Zhao-Ping Ni ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Building Blocks ◽  
Two Dimensional ◽  
Heterometallic Coordination Polymer

The first spin-crossover example of a two-dimensional coordination polymer containing [Pd(SCN)4]2− building blocks was explored.

scholarly journals Crystal structure of two-dimensional coordination polymer poly-[μ2-azido-aqua-(μ2-pyrazine-2-carboxylato-κ3O,N:N′)nickel(II)], C5H5N5O3Ni

2016 ◽  
Vol 231 (4) ◽  
pp. 1163-1164
Author(s):  
Yu Youzhu ◽  
Guo Yuhua ◽  
Yang Liguo ◽  
Niu Yongsheng
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Two Dimensional

AbstractC5H5N5O3Ni, monoclinic, C2/c (no. 15), a = 8.5804(17) Å, b = 13.790(3) Å, c = 13.969(3) Å, β = 104.37(3)°, V =1601.2(6)Å3, Z = 8, Rgt(F) = 0.0203, wRref(F2) = 0.0550, T = 293 K.

A two-dimensional CdII coordination polymer with 2,2′-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands

2014 ◽  
Vol 70 (5) ◽  
pp. 517-521
Author(s):  
Yu-Xiu Jin ◽  
Fang Yang ◽  
Li-Min Yuan ◽  
Chao-Guo Yan ◽  
Wen-Long Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Phen Ligand ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Carboxylate Groups ◽  
Phenanthroline Ligand ◽  
Phenanthroline Ligands

In poly[[μ3-2,2′-(disulfanediyl)dibenzoato-κ5 O:O,O′:O′′,O′′′](1,10-phenanthroline-κ2 N,N′)cadmium(II)], [Cd(C14H8O4S2)(C12H8N2)] n , the asymmetric unit contains one CdII cation, one 2,2′-(disulfanediyl)dibenzoate anion (denoted dtdb2−) and one 1,10-phenanthroline ligand (denoted phen). Each CdII centre is seven-coordinated by five O atoms of bridging/chelating carboxylate groups from three dtdb2− ligands and by two N atoms from one phen ligand, forming a distorted pentagonal–bipyramidal geometry. The CdII cations are bridged by dtdb2− anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture via a combination of aromatic C—H...π and π–π interactions. The thermogravimetric and luminescence properties of this compound were also investigated.

Sign in / Sign up

Export Citation Format

Share Document