Crystal structure ofcis-bis(μ-β-alanine-κ2O:O′)bis[trichloridorhenium(III)](Re–Re) sesquihydrate
2015 ◽
Vol 71
(1)
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pp. 45-47
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Keyword(s):
The structure of the title compound, [Re2Cl6(C3H7NO2)2]·1.5H2O, comprises a dinuclear complex cation [Re—Re = 2.2494 (3) Å] involvingcis-oriented double carboxylate bridges, four equatorial chloride ions and two weakly bonded chloride ligands in the axial positions at the two rhenium(III) atoms. In the crystal, two complex molecules and two water molecules constitute hydrogen-bonded dimers, while an extensive hydrogen-bonding network involving the groups of the zwitterionic ligand is important for generation of the framework. An additional partially occupied water molecule is disordered over two sets of sites about a symmetry centre with a site-occupancy ratio of 0.3:0.2.
2013 ◽
Vol 69
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pp. m598-m599
2007 ◽
Vol 63
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pp. m2657-m2658
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2015 ◽
Vol 71
(10)
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pp. 1219-1221
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2014 ◽
Vol 70
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pp. i9-i10
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Keyword(s):
2022 ◽
Vol 78
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Keyword(s):
2006 ◽
Vol 62
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pp. m796-m798
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2015 ◽
Vol 71
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pp. 1165-1168