Crystal structure of a second polymorph of tricarbonyl(N-methylpyridine-2-carboxamide-κ2N1,O)(thiocyanato-κN)rhenium(I)
2016 ◽
Vol 72
(10)
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pp. 1386-1389
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A new polymorph of the title compound, [Re(NCS)(C7H8N2O)(CO)3], crystallizing in the space groupP21/n, has been obtained and structurally characterized by the experiment and DFT calculations. In this complex, the rhenium(I) cation is octahedrally coordinated by three carbonyl groups in a facial configuration, theN,O-bidentateN-methylpyridine-2-carboxamide ligand and theN-bonded thiocyanate anion. Neighbouring molecules are linked into a three-dimensional network by intermolecular N—H...S and C—H...S interactions.
2016 ◽
Vol 72
(2)
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pp. 114-116
2016 ◽
Vol 72
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pp. 1219-1222
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2014 ◽
Vol 70
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pp. o1130-o1130
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2015 ◽
Vol 71
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pp. o719-o720
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2021 ◽
Vol 77
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pp. 42-46
2015 ◽
Vol 71
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pp. m275-m276
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2015 ◽
Vol 71
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pp. o291-o292
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2014 ◽
Vol 70
(9)
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pp. o1029-o1030
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