The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-dimethylhydrazin-1-ylidene)methyl]-1′-(diphenylphosphorothioyl)ferrocene
2018 ◽
Vol 74
(2)
◽
pp. 133-136
Keyword(s):
The asymmetric unit of the title compound, [Fe(C8H11N2)(C17H14PS)], contains two independent molecules (A and B) with very similar conformations. Each molecule is built up from a ferrocene unit substituted in the 1 and 1′ positions by a protected sulfur diphenylphosphine and by a dimethylhydrazine, –C(H)=N—N(CH3)2, fragment. The two independent molecules are linked by a C—H...N hydrogen bond. In the crystal, the A–B dimer is linked by a pair of C—H...S hydrogen bonds, forming a centrosymmetric four-molecule arrangement. These units are linked by C—H...π interactions, forming a supramolecular three-dimensional structure.
2014 ◽
Vol 70
(11)
◽
pp. 322-324
◽
Keyword(s):
2014 ◽
Vol 70
(11)
◽
pp. 418-420
◽
2015 ◽
Vol 71
(2)
◽
pp. o123-o124
◽
2014 ◽
Vol 70
(4)
◽
pp. o505-o505
◽
2016 ◽
Vol 72
(4)
◽
pp. 463-466
2014 ◽
Vol 70
(2)
◽
pp. o145-o146
2015 ◽
Vol 71
(12)
◽
pp. o1057-o1058
◽
2013 ◽
Vol 69
(11)
◽
pp. o1722-o1722
2015 ◽
Vol 71
(1)
◽
pp. o43-o44
◽
Keyword(s):