Crystal structure and Hirshfeld surface analysis of (E)-1-(4-chlorophenyl)-2-[2,2-dichloro-1-(4-fluorophenyl)ethenyl]diazene
2019 ◽
Vol 75
(4)
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pp. 465-469
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Keyword(s):
In the title compound, C14H8Cl3FN2, the planes of the 4-fluorophenyl ring and the 4-chlorophenyl ring make a dihedral angle of 56.13 (13)°. In the crystal, molecules are stacked in a column along the a axis via a weak C—H...Cl hydrogen bond and face-to-face π–π stacking interactions [centroid–centroid distances = 3.8615 (18) and 3.8619 (18) Å]. The crystal packing is further stabilized by short Cl...Cl contacts. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from Cl...H/H...Cl (31.2%), H...H (14.8%), C...H/H...C (14.0%), F...H/H...F (12.8%), C...C (9.0%) and Cl...Cl (6.7%) interactions.
2021 ◽
Vol 77
(11)
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2019 ◽
Vol 75
(8)
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pp. 1190-1194
2021 ◽
Vol 77
(6)
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pp. 596-599
Keyword(s):
2021 ◽
Vol 77
(9)
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2021 ◽
Vol 77
(8)
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pp. 834-838
2017 ◽
Vol 73
(4)
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pp. 524-527
2019 ◽
Vol 75
(2)
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pp. 237-241
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Keyword(s):
2021 ◽
Vol 77
(4)
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pp. 356-359
Keyword(s):
2018 ◽
Vol 74
(3)
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pp. 385-389
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2020 ◽
Vol 76
(6)
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pp. 811-815
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