Crystal structure and Hirshfeld surface analysis of 4-{[(E)-4-(heptyloxy)benzylidene]amino}-N-(naphthalen-2-yl)-1,3-thiazol-2-amine
2020 ◽
Vol 76
(7)
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pp. 1092-1095
Keyword(s):
In the title compound, C27H28N2OS, the naphthalene unit is planar to within 0.015 (2) Å and makes a dihedral angle of 14.24 (16)° with the thiazole ring. The anisole ring is inclined to the thiazole ring by a dihedral angle of 13.18 (23)°. The torsion angle between the heptyl chain and the anisole ring is 61.1 (4)°. These dihedral and torsion angles render the molecule non-planar. In the crystal, molecules are linked by C—H...π interactions, forming zigzag chains that propagate parallel to the b axis. The roles of the various intermolecular interactions in the crystal packing were clarified by Hirshfeld surface analysis; the most important contributions are from H...H (51.5%) and C...H/H...C (31.8%) contacts.
2018 ◽
Vol 74
(12)
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pp. 1746-1750
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2019 ◽
Vol 75
(6)
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pp. 830-833
2020 ◽
Vol 76
(6)
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pp. 920-923
2019 ◽
Vol 75
(1)
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pp. 94-98
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2020 ◽
Vol 76
(7)
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pp. 1122-1125
2018 ◽
Vol 74
(5)
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pp. 703-708
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Keyword(s):
2020 ◽
Vol 76
(5)
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pp. 605-610
2022 ◽
Vol 78
(1)
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Keyword(s):
2017 ◽
Vol 73
(4)
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pp. 524-527
2019 ◽
Vol 75
(2)
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pp. 237-241
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Keyword(s):