catena-Poly[[bis{2-[3-(carboxymethyl)adamantan-1-yl]acetato-κ2O,O′}cadmium(II)]-μ-N,N′-bis(pyridine-4-carboxamido)piperazine-κ2N:N′]
Keyword(s):
In the title compound, [Cd(C14H19O4)2(C16H16N4O2)]n, the CdIIcation is coordinated in a distorted octahedral fashion bytranspyridyl N-atom donors from twoN,N′-bis(pyridine-4-carboxamido)piperazine (bpcp) ligands, and chelating carboxylate groups from two 2-[3-(carboxymethyl)adamantan-1-yl]acetate ligands. [Cd(adaH)(bpcp)]ncoordination polymer chains are oriented along [-111] and aggregate into supramolecular layers parallel to (122) by O—H...O hydrogen-bonding interactions. The supramolecular three-dimensional crystal structure is then constructed by interlayer C—H...O non-classical interactions. The O atoms of one of the carboxylate groups were refined as disordered over two sets of sites, with occupancies 0.553 (7) and 0.447 (7).
2015 ◽
Vol 71
(2)
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pp. 136-139
2006 ◽
Vol 62
(4)
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pp. m796-m798
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Keyword(s):
2015 ◽
Vol 71
(1)
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pp. 73-75
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2007 ◽
Vol 63
(3)
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pp. m761-m763
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2015 ◽
Vol 71
(10)
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pp. 903-907
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2012 ◽
Vol 68
(4)
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pp. m402-m403
2017 ◽
Vol 73
(9)
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pp. 1279-1281
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