Green synthesis and spectroscopic studies of some complexes compounds as pigments and their applications in paints

2017 ◽  
Vol 46 (4) ◽  
pp. 286-295 ◽  
Author(s):  
Osama A.G. Wahba ◽  
Ali M. Hassan ◽  
Abdelrahman M. Naser ◽  
Adel M.G. Hanafi

Purpose The purpose of this study to investigate the synthesis of new Cr(III), Fe(III), Ni(II) and Cu(II) Schiff base complexes by a simple technique (microwave technique). The evaluation of the prepared complexes as pigments as corrosion resistant was also explored. Design/methodology/approach The Schiff base complexes were prepared by using microwave method (green chemistry), and then, the physico-chemical requirements according to standards for the synthesised pigments were investigate. Findings The prepared complexes exhibit good physical, mechanical and corrosion properties as pigments in paint formulations. Research limitations/implications The simple technique used for synthesis of metal complex pigments will significantly increase the cost saving for the manufacturing of such pigments category. Also, the used technique is considered a green method (eco-friendly), as there no organic solvent was used. Practical implications The evaluation of the prepared complex pigments as corrosion resistants was also studied. Originality/value It is a simple technique, green synthesis (no solvent used) is involved and high yield is obtained.

2014 ◽  
Vol 692 ◽  
pp. 240-244
Author(s):  
Gong De Wu ◽  
Xiao Li Wang ◽  
Zhi Li Zhai

A series of transition metal alanine-salicylaldehyde Schiff base chromium (III) complexes immobilized on MCM-41 were prepared and characterized by various physico-chemical measurements such as FIIR, XRD, HRTEM, N2 sorption and elemental analysis. The immobilized complexes were effective and stable catalysts for the epoxidation of styrene and cyclohexene with 30% hydrogen peroxide. Moreover, the metal centers were found to play important roles in the catalytic performance of immobilized complex catalysts.


2009 ◽  
Vol 62 (20) ◽  
pp. 3377-3383 ◽  
Author(s):  
Akila A. Saleh ◽  
Abdel Razak M. Tawfik ◽  
Mosad A. El Ghamry ◽  
Samy M. Abu-el-wafa

1981 ◽  
Vol 43 (3) ◽  
pp. 525-531 ◽  
Author(s):  
G.K. Joshi ◽  
M.P. Bhutra ◽  
Sudhindra N. Misra

2014 ◽  
Vol 39 (6) ◽  
pp. 623-632 ◽  
Author(s):  
Maryam Hasanzadeh ◽  
Mehdi Salehi ◽  
Maciej Kubicki ◽  
Seyyed Mohammad Shahcheragh ◽  
Grzegorz Dutkiewicz ◽  
...  

2020 ◽  
Vol 5 (33) ◽  
pp. 10256-10268 ◽  
Author(s):  
Hanadi Katouah ◽  
Ahmed M. Hameed ◽  
Arwa Alharbi ◽  
Fatmah Alkhatib ◽  
Reem Shah ◽  
...  

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