Effects of graft density on the separation performance of temperature-responsive materials under the same graft chain length

Author(s):  
Dandan Yang ◽  
Yanli Liang ◽  
Rongji Dai ◽  
Yulin Deng
2019 ◽  
Vol 10 (42) ◽  
pp. 5686-5720 ◽  
Author(s):  
Amin Abdollahi ◽  
Hossein Roghani-Mamaqani ◽  
Bahareh Razavi ◽  
Mehdi Salami-Kalajahi

Light-controlling of phase separation in temperature-responsive polymer solutions by using light-responsive materials for reversible controlling physical and chemical properties of the media with an out-of-system stimulus with tunable intensity.


2009 ◽  
Vol 610-613 ◽  
pp. 1198-1202 ◽  
Author(s):  
Yu Zhang ◽  
Jing Liang Xu ◽  
Zhen Hong Yuan

Enzymes, immobilized on pH/temperature/ion-responsive carriers, relieve poor contact and could be conveniently recycled as well. Enzymes were immobilized on pH-responsive carriers often by covalent method, which was better than non-covalent method (adsorption). The immobilized enzymes showed slight steric hindrance for enzymatic reaction, but always lose much activity during recycle process. The Km values were often increased significantly via immobilization on temperature/ion responsive carriers, while the immobilized enzymes expressed superior reusability. Both covalent and non-covalent methods were fit for enzymes to be immobilized on temperature-responsive carriers. Non-covalent method (entrapment) was preferential choose for enzymes to be immobilized on ion-responsive carriers. Many drawbacks, such as large activity loss and slow respondence during stimulus occurrence, seriously restrained the effect of the immobilized enzymes. It was supposed to open up special stimuli-responsive materials for enzymes immobilization, and choose proper immobilization methods, correspondingly.


2004 ◽  
Vol 847 ◽  
Author(s):  
Suneel Bandi ◽  
David A. Schiraldi

AbstractClay aerogels are a relatively unexplored form of matter that are only now being investigated for use in the reinforcement of organic polymers. We have recently demonstrated an efficient process for producing these aerogels; we now report our preliminary work describing the preparation and properties of polymer/clay aerogel composites, including temperature-responsive materials.


RSC Advances ◽  
2015 ◽  
Vol 5 (89) ◽  
pp. 73217-73224 ◽  
Author(s):  
Yuki Hiruta ◽  
Yuhei Nagumo ◽  
Atsushi Miki ◽  
Teruo Okano ◽  
Hideko Kanazawa

Even using the same homo poly(N-isopropylacrylamide) immobilized silica beads as stationary phases, terminal functional group and chain length significantly affected temperature-dependent elution behavior of steroids.


2017 ◽  
Vol 142 ◽  
pp. 226-233 ◽  
Author(s):  
Mi Hee Ryu ◽  
Jeyoung Park ◽  
Dongyeop X. Oh ◽  
Sung Yeon Hwang ◽  
Hyeonyeol Jeon ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (74) ◽  
pp. 69930-69938 ◽  
Author(s):  
Jinxian Yang ◽  
Lianwei Li ◽  
Chunfeng Ma ◽  
Xiaodong Ye

The effects of chain length and graft density of poly(2-ethyl-2-oxazoline) on the protein resistance of degradable polyurethane-graft-poly(2-ethyl-2-oxazoline) with PCL as the soft segment have been investigated.


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