Charge storage ability in polypyrrole. Influence of the conditions of synthesis.

ABSTRACTThe evolution of the capacity to store electrical charges of electrogenerated polypyrrole and polythiophene films, as a function of the parameters of synthesis (electrical potential, solvent, Monomer concentration and temperature) was analyzed. The polymer production was followed by “ex situ” ultramicrogravimetry. The stored charge in each film was controlled by voltammetry and chronoamperometry, in the background electrolyte (in absence of Monomer). The charge storage ability was calculated from the ratio between stored charge and polymer mass adhered to the electrode. The charge storage ability of an electrogenerated film decreases several times when one of the parameters of synthesis: potential of polymerization, temperature, concentration of monomer or donor number of the solvent, increase. The change on the polymer property when the conditions of synthesis shift, points to a mixed polymerization-degradation process during polymer growth. The knowledge of those variations allows to optimize the conditions of synthesis to generate conducting polymers for specific batteries applications.

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Cathodic electrodeposition of CdMn2O4 nanoplates and evaluation of the charge storage ability

Journal of Solid State Electrochemistry ◽

10.1007/s10008-020-04600-7 ◽

2020 ◽

Vol 24 (5) ◽

pp. 1231-1238

Author(s):

Hamid Reza Moazami ◽

Saied Saeed Hosseiny Davarani ◽

Nasrin Ghassemi ◽

Sara Hamed

Keyword(s):

Charge Storage ◽

Cathodic Electrodeposition ◽

Storage Ability

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Charge storage ability of the gold nanoparticles: Towards the performance of a supercapacitor

Applied Surface Science ◽

10.1016/j.apsusc.2017.01.258 ◽

2017 ◽

Vol 424 ◽

pp. 151-156 ◽

Cited By ~ 7

Author(s):

Meenakshi Choudhary ◽

Samarjeet Siwal ◽

Debkumar Nandi ◽

Kaushik Mallick

Keyword(s):

Gold Nanoparticles ◽

Charge Storage ◽

Storage Ability

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A facile route to preparation of Co3O4 nanoplates and investigation of their charge storage ability as electrode material for supercapacitors

Journal of Materials Science Materials in Electronics ◽

10.1007/s10854-016-4882-x ◽

2016 ◽

Vol 27 (8) ◽

pp. 8623-8632 ◽

Cited By ~ 13

Author(s):

Mustafa Aghazadeh ◽

Rohollah Ahmadi ◽

Davoud Gharailou ◽

Mohammad Reza Ganjali ◽

Parviz Norouzi

Keyword(s):

Electrode Material ◽

Charge Storage ◽

Facile Route ◽

Storage Ability

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Influence of grid voltage on charge storage ability of porous PTFE film electret s

Acta Physica Sinica ◽

10.7498/aps.52.3186 ◽

2003 ◽

Vol 52 (12) ◽

pp. 3186

Author(s):

Wu Yue-Hua ◽

Xia Zhong-Fu ◽

Wang Fei-Peng ◽

Qiu Xun-Lin

Keyword(s):

Charge Storage ◽

Ptfe Film ◽

Grid Voltage ◽

Storage Ability

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Solvent effects on the charge storage ability in polypyrrole

Electrochimica Acta ◽

10.1016/s0013-4686(98)00313-2 ◽

1999 ◽

Vol 44 (12) ◽

pp. 2053-2059 ◽

Cited By ~ 46

Author(s):

T.F Otero ◽

I Cantero ◽

H Grande

Keyword(s):

Solvent Effects ◽

Charge Storage ◽

Storage Ability

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HIGH PRECISION SIMULATION ON SURFACE POTENTIAL OF CELLULAR ELECTRETS BY CHARGE SIMULATION METHOD

Surface Review and Letters ◽

10.1142/s0218625x18501330 ◽

2019 ◽

Vol 26 (01) ◽

pp. 1850133

Author(s):

J. W. ZHANG ◽

X. CHEN ◽

Y. S. ZHAO ◽

Z. Y. SU ◽

R. T. LIU

Keyword(s):

Corona Discharge ◽

High Precision ◽

Surface Potential ◽

Simulation Method ◽

Charge Storage ◽

Charge Simulation Method ◽

Storage Performance ◽

Simulation Based ◽

Electrostatic Generator ◽

Storage Ability

Surface potential is one of the key properties of charge retain ability and energy storage performance of cellular electrets. Based on charge simulation method (CSM), a high precision simulation algorithm of surface potential of functional dielectrics is proposed in this paper, which can be applied to the simulations of cellular polypropylene after high-voltage corona discharge. In order to validate the modeling, the surface potential of insulating polymer after corona discharge is measured by an electrostatic measurement system and compared with simulation results based on CSM and finite element method (FEM). The result shows that the numerical simulation based on CSM is well consistent with the experimental data, which indicates that the modeling based on CSM can be used in the calculation and analysis of charge storage ability of capacitor and electrostatic generator based on functional electrets. Moreover, as simulation based on CSM has higher precision than FEM, investigation of surface charge storage ability and prediction of electrostatic hazards of insulating dielectrics could be realized by using CSM.

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