Ti-Rich Nonstoichiometric BaTiO3: I, High-Temperature Electrical Conductivity Measurements

1971 ◽  
Vol 54 (10) ◽  
pp. 515-519 ◽  
Author(s):  
S. A. LONG ◽  
R. N. BLUMENTHAL
1997 ◽  
Vol 481 ◽  
Author(s):  
Michael F. Bell ◽  
Georges Dénès ◽  
Zhimeng Zhu

ABSTRACTPrecipitation reactions from aqueous solutions of calcium nitrate and tin(II) fluoride result in the formation of two metastable phases, depending on the reaction conditions. Crystalline CaSn2F6 and the microcrystalline Ca1-xSnxF2 solid solution are obtained, the latter crystallizing in the cubic fluorite (CaF2) type with total Ca/Sn disorder. Both phases are fluoride ion conductors. Electrical conductivity measurements versus temperature and bulk density measurements show that both phases are far from thermodynamic equilibrium at ambient conditions, and thus are metastable. Both decompose to a mixture of SnF2 and CaF2 at high temperature. In addition, CaSn2F6 is chemically unstable in an aqueous medium, in which it looses SnF2 to give the microcrystalline Ca1-xSnxF2 solid solution.


2010 ◽  
Vol 405 (1) ◽  
pp. 53-56 ◽  
Author(s):  
Xiaoping Wu ◽  
Baohua Zhang ◽  
Junshan Xu ◽  
Tomoo Katsura ◽  
Shuangmeng Zhai ◽  
...  

2013 ◽  
Vol 42 (7) ◽  
pp. 1319-1323 ◽  
Author(s):  
S. Boldrini ◽  
A. Famengo ◽  
F. Montagner ◽  
S. Battiston ◽  
S. Fiameni ◽  
...  

2021 ◽  
Author(s):  
Yoshinobu Adachi ◽  
Naoyuki Hatada ◽  
Masaki Kato ◽  
Ken Hirota ◽  
Tetsuya Uda

Accurate electrical conductivity measurements of LaNi1−xFexO3 using fully dense polycrystalline samples revealed that LaNiO3 (x = 0) has the highest electrical conductivity among precious-metal-free oxides in high-temperature oxidizing atmospheres.


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