ELECTRICAL DOUBLE LAYER AT THE CALCIUM CARBONATE/ELECTROLYTE INTERFACE: MOLECULAR MODELING AND EXPERIMENTAL INSIGHTS

2019 ◽  
Author(s):  
Piotr Zarzycki ◽  
◽  
Laura N. Lammers ◽  
Marzena Prus ◽  
Christopher Colla ◽  
...  
Keyword(s):  
Molecular Modeling ◽  
Calcium Carbonate ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Electrolyte Interface

Electrical double layer at the gibbsite/anionic polyacrylamide/supporting electrolyte interface – Adsorption, spectroscopy and electrokinetic studies

2018 ◽  
Vol 261 ◽  
pp. 439-445 ◽  
Author(s):  
Katarzyna Szewczuk-Karpisz ◽  
Patrycja Krasucka ◽  
Patrycja Boguta ◽  
Kamil Skic ◽  
Zofia Sokołowska ◽  
...  
Keyword(s):  
Double Layer ◽  
Electrical Double Layer ◽  
Supporting Electrolyte ◽  
Electrolyte Interface ◽  
Anionic Polyacrylamide

The metal side of the electrical double layer at the metal/electrolyte interface

1984 ◽  
Vol 171 (1-2) ◽  
pp. 195-217 ◽  
Author(s):  
A.L.G. van den Eeden ◽  
J.H. Sluyters ◽  
J.H. van Lenthe
Keyword(s):  
Double Layer ◽  
Electrical Double Layer ◽  
Electrolyte Interface

The Electrical Double Layer at Hydrous Manganese Dioxide/Electrolyte Interface

2001 ◽  
Vol 241 (1) ◽  
pp. 112-119 ◽  
Author(s):  
Sushree Swarupa Tripathy ◽  
Sukriti Bhusan Kanungo ◽  
Santosh Kumar Mishra
Keyword(s):  
Manganese Dioxide ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Electrolyte Interface

The electrical double-layer properties of the mica (muscovite)-aqueous electrolyte interface

1981 ◽  
Vol 34 (6) ◽  
pp. 1177 ◽  
Author(s):  
JS Lyons ◽  
DN Furlong ◽  
TW Healy
Keyword(s):  
Zeta Potential ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Negative Charge ◽  
Aqueous Electrolyte ◽  
Streaming Potential ◽  
Electrolyte Interface ◽  
Muscovite Mica ◽  
Silica Alumina ◽  
Flow Apparatus

Electrophoresis and streaming potential data are reported for crushed and sheet muscovite mica respectively. For streaming potential measurements a newly designed radial flow apparatus was used. Measurements on crushed mica show that both aluminium and silicon leach out of the mica. Leached aluminium and silicon may readsorb to confer increased positive and negative charge respectively on the mica. Electrophoresis data indicate that leaching of aluminium occurs more rapidly than of silicon. Aging experiments on sheet mica show leaching effects to be much slower than on crushed mica. Streaming potential measurements on freshly cleaved mica sheets showed that (i) the zeta- potential depended strongly on electrolyte (KCl) concentration; (ii) the zeta-potential was relatively independent of pH and (iii) monovalent cations were adsorbed in the sequence H+ > Cs+ > K+ > Na+ > Li+, whilst Ca2+ adsorbed more strongly than K+. It is proposed that the structure of the electrical double layer at the mica/electrolyte interface results from the distribution of all ions between the diffuse layer, the Stern plane (hydrated) and more critically the lattice holes of the silica-alumina basal plane.

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