Quantum-Chemical Analysis of the Electron Transfer Mechanism in Model System MgNbF7 + 12MgCl2 by the Method of Frontier Molecular Orbitals

2018 ◽  
Vol 54 (9) ◽  
pp. 676-682
Author(s):  
V. G. Kremenetsky ◽  
S. A. Kuznetsov
Keyword(s):  
Electron Transfer ◽  
Chemical Analysis ◽  
Quantum Chemical ◽  
Model System ◽  
Molecular Orbitals ◽  
Transfer Mechanism ◽  
Frontier Molecular Orbitals ◽  
Quantum Chemical Analysis ◽  
Electron Transfer Mechanism

Green photocatalytic organic transformations by polyoxometalates vs. mesoporous TiO2 nanoparticles: selective aerobic oxidation of alcohols

2015 ◽  
Vol 14 (3) ◽  
pp. 563-568 ◽  
Author(s):  
Theodoros S. Symeonidis ◽  
Ioannis Tamiolakis ◽  
Gerasimos S. Armatas ◽  
Ioannis N. Lykakis
Keyword(s):  
Electron Transfer ◽  
Tio2 Nanoparticles ◽  
Aerobic Oxidation ◽  
Mesoporous Tio2 ◽  
Transfer Mechanism ◽  
Organic Transformations ◽  
Electron Transfer Mechanism ◽  
Nanoparticle Assemblies ◽  
Oxidation Of Alcohols ◽  
Aromatic Alcohols

Decatungstate supported on mesoporous TiO2 nanoparticle assemblies catalyze the selective and efficient oxidation of aromatic alcohols under “green” oxidation conditions. An electron transfer mechanism was predominated under UV-vis irradiation.

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