Thermodynamic study of sodium decyl sulfate solutions in the region of second critical micelle concentration: 2. Thermodynamic functions of polymorphic micellar transition and components of its Gibbs energy

2010 ◽  
Vol 72 (2) ◽  
pp. 216-223 ◽  
Author(s):  
V. S. Kuznetsov ◽  
N. V. Usol’tseva ◽  
V. P. Zherdev ◽  
V. V. Bykova
Author(s):  
I. N. Ganiev ◽  
S. E. Otajonov ◽  
N. F. Ibrohimov ◽  
M. Mahmudov

In the heat «cooling» investigated the temperature dependence of the specific heat capacity and thermodynamic functions doped strontium alloy AK1М2 in the range 298,15—900 K. Mathematical models are obtained that describe the change in these properties of alloys in the temperature range 298.15—900 K, as well as on the concentration of the doping component. It was found that with increasing temperature, specific heat capacity, enthalpy and entropy alloys increase, and the concentration up to 0.5 wt.% of the alloying element decreases. Gibbs energy values have an inverse relationship, i.e., temperature — decreases the content of alloying component — is up to 0.5 wt.% growing.


Author(s):  
Shipra Baluja ◽  
Kapil Bhesaniya ◽  
Rahul Bhalodia ◽  
Sumitra Chanda

The solubility of Butylated hydroxyl toluene in aqueous and alcohol solutions were determined at different temperatures (293.15 to 313.15) K. Using Van’t Hoff and Gibb’s equations, some thermodynamic functions such as Gibbs energy, enthalpy and entropy of dissolution, and of mixing of Butylated hydroxyl toluene in aqueous and alcohol solutions, were evaluated from solubility data. The solubility was greater in butanol and minimum in water. The enthalpies, entropy and Gibb’s energy of dissolution were positive for all solvents.


2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Dunya Mahammad Babanly ◽  
Qorkhmaz Mansur Huseynov ◽  
Ziya Saxaveddin Aliev ◽  
Dilgam Babir Tagiyev ◽  
Mahammad Baba Babanly

The solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode. The EMF results were used to calculate the relative partial thermodynamic functions of thallium in alloys and the standard integral thermodynamic functions (-ΔfG0, -ΔfH0, and S0298) of Tl6SBr4 compound. All data regarding thermodynamic properties of thallium chalcogen-halides are generalized and comparatively analyzed. Consequently, certain regularities between thermodynamic functions of thallium chalcogen-halides and their binary constituents as well as degree of ionization (DI) of chemical bonding were revealed.


1995 ◽  
Vol 174 (1) ◽  
pp. 156-161 ◽  
Author(s):  
Makoto Aratono ◽  
Masaaki Ikeguchi ◽  
Takanori Takiue ◽  
Norihiro Ikeda ◽  
Kinsi Motomura

2003 ◽  
Vol 39 (3-4) ◽  
pp. 453-464 ◽  
Author(s):  
Iwao Katayama ◽  
Toshihiro Tanaka ◽  
Takamichi Iida

Electromotive force method with solid electrolyte is briefly explained, and a thermodynamic study of semi conducting compound solid solution ZnTe-CdTe is picked up to show the way how thermodynamic functions of this system are obtained by several experimental methods based on our published papers and recently published data are added for comparison.


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