First example of direct phosphorylation of vinyl silanes with elemental phosphorus in superbasic media

2015 ◽  
Vol 85 (10) ◽  
pp. 2416-2417 ◽  
Author(s):  
A. V. Artem’ev ◽  
N. K. Gusarova ◽  
A. O. Korocheva ◽  
E. A. Matveeva ◽  
B. A. Trofimov
Keyword(s):  
Elemental Phosphorus ◽  
Vinyl Silanes ◽  
Superbasic Media

The synthesis and polymerization of vinyl silanes possessing two functional groups on the silicon atom

1977 ◽  
Vol 19 (4) ◽  
pp. 868-874 ◽  
Author(s):  
K.A. Andrianov ◽  
N.V. Delazari ◽  
N.A. Yemel'kina ◽  
Z.V. Pechorkina ◽  
L.A. Leites
Keyword(s):  
Functional Groups ◽  
Silicon Atom ◽  
Vinyl Silanes

Structure of the product of the reaction of elemental phosphorus, propylene oxide, phenol, and triethylamine

1989 ◽  
Vol 38 (10) ◽  
pp. 2062-2065
Author(s):  
B. E. Ivanov ◽  
N. S. Fridland ◽  
S. S. Krokhina ◽  
D. R. Sharafutdinova ◽  
Yu. Ya. Efremov
Keyword(s):  
Propylene Oxide ◽  
Elemental Phosphorus

scholarly journals Non-Selective Dimerization of Vinyl Silanes by the Putative (Phenanthroline)PdMe Cation to 1,4-Bis(trialkoxysilyl)butenes

Inorganics ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 102
Author(s):  
Sandun Perera ◽  
Michael Findlater
Keyword(s):  
Nmr Spectroscopy ◽  
Palladium Complex ◽  
Organic Products ◽  
Vinyl Silanes ◽  
In Situ Nmr Spectroscopy ◽  
In Situ Nmr ◽  
Moderate Yield

Activation of the dialkylpalladium complex (phen)Pd(CH3)2 (phen = 1,10-phenanthroline) with B(C6F5)3 affords a competent catalyst for the dimerization of vinyl silanes. All organic products of the catalytic dimerization of trialkoxyvinylsilanes were characterized by in situ NMR spectroscopy and GC–MS. The putative palladium cation was characterized by NMR spectroscopy. Upon activation, the palladium complex generated products in moderate yield (60–70%) and selectivity (~60:40, dimer:disproportionation products).

Expedient one-pot organometallics-free synthesis of tris(2-pyridyl)phosphine from 2-bromopyridine and elemental phosphorus

2012 ◽  
Vol 53 (19) ◽  
pp. 2424-2427 ◽  
Author(s):  
Boris A. Trofimov ◽  
Alexander V. Artem’ev ◽  
Svetlana F. Malysheva ◽  
Nina K. Gusarova ◽  
Nataliya A. Belogorlova ◽  
...  
Keyword(s):  
Elemental Phosphorus ◽  
One Pot

Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

2018 ◽  
Vol 54 (92) ◽  
pp. 12994-12997 ◽  
Author(s):  
Qiu-Chao Mu ◽  
Xing-Ben Wang ◽  
Fei Ye ◽  
Yu-Li Sun ◽  
Xing-Feng Bai ◽  
...  
Keyword(s):  
Alkyl Halides ◽  
One Pot ◽  
Migratory Insertion ◽  
Palladium Catalyzed ◽  
Vinyl Silanes

One-pot formation of (E)-vinyl silanes and (E)-silyl-substituted α, β-unsaturated amides could be completed easily via palladium carbene migratory insertion in good yields and high chemoselectivity.

Tandem photochemical or thermal [1,5]-H, thermal [1,5]-Si migrations of vinyl silanes

1993 ◽  
Vol 34 (51) ◽  
pp. 8217-8220 ◽  
Author(s):  
Michael C. Pirrung ◽  
Yong Rok Lee
Keyword(s):  
Vinyl Silanes
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