Partial and complete oxidation of brown coal in a supercritical water–oxygen fluid under conditions of counterflowing reactant streams

2016 ◽  
Vol 10 (8) ◽  
pp. 1256-1263 ◽  
Author(s):  
A. A. Vostrikov ◽  
D. Yu. Dubov ◽  
M. Ya. Sokol ◽  
O. N. Fedyaeva
2016 ◽  
Vol 107 ◽  
pp. 707-714 ◽  
Author(s):  
Anatoly A. Vostrikov ◽  
Andrey V. Shishkin ◽  
Mikhail Ya. Sokol ◽  
Dmitriy Yu. Dubov ◽  
Oxana N. Fedyaeva

2007 ◽  
Vol 41 (6) ◽  
pp. 323-330
Author(s):  
O. N. Fedyaeva ◽  
A. A. Vostrikov ◽  
D. Yu. Dubov ◽  
S. A. Psarov ◽  
M. Ya. Sokol

2017 ◽  
Vol 126 ◽  
pp. 55-64 ◽  
Author(s):  
Oxana N. Fedyaeva ◽  
Vladimir R. Antipenko ◽  
Anatoly A. Vostrikov

2001 ◽  
Vol 20 (1-6) ◽  
pp. 385-392 ◽  
Author(s):  
M. Fujie ◽  
A. Inui ◽  
K. J. Anjo ◽  
T. Sugeta ◽  
T. Sako ◽  
...  

2016 ◽  
Vol 25 (1) ◽  
pp. 55-66 ◽  
Author(s):  
A. A. Vostrikov ◽  
D. Yu. Dubov ◽  
M. Ya. Sokol ◽  
A. V. Shishkin ◽  
O. N. Fedyaeva

2013 ◽  
Vol 726-731 ◽  
pp. 2714-2717
Author(s):  
Zhi Yuan Ning ◽  
Qing Qing Guan ◽  
Ping Ning ◽  
Jun Jie Gu

Phenol is hardly gasified in supercritical water (SCW) under the temperature 450 °C, at which cleavages of aromatic ring occur difficultly. Partial oxidative gasification provides a potential way to remove phenol for hydrogen at those temperatures. The results showed that even O2 was less than the required amount for complete oxidation by stoichiometry, effective gasification of phenol in SCW was took place. About 76 % of phenol was removed and 2.7 mol/mol of hydrogen was produced with Na2CO3 as catalyst at 180s, O/Phenol 7.5, 450 °C and 24 MPa. The process also indicated partial oxidation of phenol produced some opening-rings products such oxalic and maleic acid, which were slowly gasified. Specifically, at lower O/Phenol ratios, the gasification reaction was predominant which led higher yields of H2, while at higher O/Phenol ratios, the oxdication predominated, which increased the amount of CO2 with less H2.


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