Liquid-liquid equilibrium in the water-ethanol-toluene system. Correlation of equilibrium data

Liquid-liquid equilibrium data in the water-ethanol-toluene system were correlated by the superposition of the Wilson and Redlich-Kister equations with a ternary term. The correlation of both homogeneous binary systems was taken from the literature. The ternary liquid-liquid equilibrium data were at all temperatures satisfactorily described on using only three ternary parameters determined from the equilibrium data at 50 °C. The parameters obtained by the correlation yield also a good estimate of boiling point and composition of homogeneous azeotropic mixture.

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Isothermal and isobaric vapour-liquid equilibrium data in the tetrachloromethane-sec-butyl alcohol system

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19832446 ◽

1983 ◽

Vol 48 (9) ◽

pp. 2446-2453 ◽

Cited By ~ 6

Author(s):

Jan Linek

Keyword(s):

Experimental Data ◽

Boiling Point ◽

Butyl Alcohol ◽

Correlation Equations ◽

Wilson Equation ◽

Liquid Equilibrium ◽

Raoult’S Law ◽

System A ◽

Equilibrium Data ◽

Alcohol System

Isothermal vapour-liquid equilibrium data at 65, 73 and 80 °C and isobaric ones at 101.3 kPa were measured in the tetrachloromethane-sec-butyl alcohol system. A modified circulation still of the Gillespie type was used for the measurements. Under the conditions of measurement, the system exhibits positive deviations from Raoult's law and minimum boiling-point azeotropes. The experimental data were fitted to a number of correlation equations, the most suitable being the Wilson equation.

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Liquid-liquid equilibrium data collection, Vol. V, Part 1-3 (Binary Systems, Ternary Systems, Ternary and Quarternary Systems). Von J. M. Sorensen und W. Arlt. Herausgeg. von D. Behrens und R. Eckermann, DECHEMA, Deutsche Gesellschaft für Chemisches Appar

Chemie Ingenieur Technik ◽

10.1002/cite.330531121 ◽

1981 ◽

Vol 53 (11) ◽

pp. 910-910

Author(s):

Th. Pilhofer

Keyword(s):

Data Collection ◽

Binary Systems ◽

Ternary Systems ◽

Deutsche Gesellschaft ◽

Liquid Equilibrium ◽

Equilibrium Data

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Vapor−Liquid Equilibrium Data for Acetone + Methanol + Benzene, Chloroform + Methanol + Benzene, and Constituent Binary Systems at 101.3 kPa

Journal of Chemical & Engineering Data ◽

10.1021/je990470c ◽

2000 ◽

Vol 45 (2) ◽

pp. 410-410 ◽

Cited By ~ 1

Author(s):

Kiyofumi Kurihara ◽

Hiroaki Hori ◽

Kazuo Kojima

Keyword(s):

Binary Systems ◽

Liquid Equilibrium ◽

Vapor Liquid Equilibrium ◽

Equilibrium Data ◽

Chloroform Methanol ◽

Constituent Binary ◽

Vapor Liquid

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Liquid-liquid equilibrium in the water-ethanol-toluene system. Experimental results

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19890581 ◽

1989 ◽

Vol 54 (3) ◽

pp. 581-585 ◽

Cited By ~ 5

Author(s):

Květuše Říčná ◽

Jaroslav Matouš ◽

Josef P. Novák ◽

Vladimír Kubíček

Keyword(s):

Distribution Coefficient ◽

Boiling Point ◽

Normal Pressure ◽

Experimental Results ◽

Azeotropic Mixture ◽

Liquid Equilibrium

Liquid-liquid equilibrium at 5, 25, and 50 °C was measured in the water-ethanol-toluene system. Special attention was paid to the determination of distribution coefficient of ethanol. Besides, the composition and boiling point of azeotropic mixture at normal pressure were determined.

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