Dehalogenation of Chloroarenes with Sodium Dihydridobis(2-methoxyethoxo)aluminate in the Presence of Transition Metal Compounds
1994 ◽
Vol 59
(7)
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pp. 1645-1653
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Keyword(s):
Dehalogenation of low-chlorinated arenes such as p-dichlorobenzene or chlorobenzene with the title hydride is accelerated in the presence of transition metal species formed in situ from the corresponding 2,4-pentanedionates. Their efficiency decreases in the order: Co ≈ Ni ≈ Pd > Cu >> Mn > Fe which results from changes of their activity and stability. The dehalogenation is well described by a kinetic model consisting of the set of dehalogenation steps which are first order in the chloroarene combined with the catalyst deactivation which is second order in the transition metal compound.
Keyword(s):
2013 ◽
Vol 28
(9)
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pp. 907-915
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2002 ◽
Vol 189
(2)
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pp. 373-388
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1980 ◽
Vol 34
(1)
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pp. 45-50
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Keyword(s):