Instability of Solutions of Quaternary Ammonium Permanganates in Dichloromethane
1997 ◽
Vol 62
(6)
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pp. 849-854
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The paper deals with instability of solutions of quaternary ammonium permanganates, QMnO4 (Q = tetraethyl-, tetra-1-propyl-, tetra-1-butyl-, tetra-1-pentyl-, tetra-1-octyl-, and cetyltrimethylammonium), in dichloromethane and presents the rate constants and activation parameters of the reduction of permanganate. Attention was paid to the properties of colloidal Mn(IV) intermediate. The stability of the solutions depends markedly on the quaternary ammonium salt used.
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Keyword(s):
2013 ◽
Vol 34
(1)
◽
pp. 106-110
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2007 ◽
Vol 98
(3)
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pp. 209-218
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