Geochemistry and tectonic significance of alkalic mafic magmatism in the Yukon-Tanana terrane, Finlayson Lake region, Yukon

2002 ◽  
Vol 39 (12) ◽  
pp. 1729-1744 ◽  
Author(s):  
Stephen J Piercey ◽  
James K Mortensen ◽  
Donald C Murphy ◽  
Suzanne Paradis ◽  
Robert A Creaser

This paper provides an integrated field and geochemical study of weakly alkalic, ~360 Ma mafic rocks from the Yukon–Tanana terrane in the Finlayson Lake region, southeastern Yukon. These mafic rocks occur as dykes and sills that crosscut older felsic metavolcanic rocks and metasedimentary rocks (Kudz Ze Kayah unit) or as flows interlayered with carbonaceous metasedimentary rocks. The mafic rocks have signatures similar to those of ocean-island basalts, moderate TiO2 and P2O5 contents, elevated high field strength element and light rare earth element contents, and εNd350 = +1.1. A subset of the dykes (group 4b) has similar geochemical characteristics but with higher Th/Nb and lower Nb/U ratios, higher Zr and light rare earth element contents, and εNd350 = –2.8. The geochemical and isotopic attributes of these rocks are consistent with formation from either lithospheric or asthenospheric sources during decompression melting of the mantle, with some rocks exhibiting evidence for crustal contamination (group 4b). The alkalic basalts are interpreted to represent ~360 Ma ensialic back-arc rifting and basin generation. It is envisioned that east-dipping subduction, represented by slightly older magmatic suites (Fire Lake unit), was disrupted by subduction hinge roll-back, westward migration of arc magmatism, and the onset of back-arc extension. Decompression melting of the mantle associated with back-arc generation resulted in mantle melting and the formation of the alkalic basalts. The spatial association of this mafic magmatism with crustally derived felsic volcanic rocks and contained volcanogenic massive sulphide mineralization suggests that the associated deposits (Kudz Ze Kayah, GP4F) formed within an ensialic back-arc environment.

Minerals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 405 ◽  
Author(s):  
Bradley Cave ◽  
Richard Lilly ◽  
Stijn Glorie ◽  
Jack Gillespie

The Ernest Henry Iron-Oxide-Copper-Gold deposit is the largest known Cu-Au deposit in the Eastern Succession of the Proterozoic Mount Isa Inlier, NW Queensland. Cu-Au mineralization is hosted in a K-feldspar altered breccia, bounded by two major pre-mineralization shear zones. Previous research suggests that Cu-Au mineralization and the ore-bearing breccia formed simultaneously through an eruption style explosive/implosive event, facilitated by the mixing of fluids at ~1530 Ma. However, the preservation of a highly deformed, weakly mineralized, pre-mineralization feature (termed the Inter-lens) within the orebody indicates that this model must be re-examined. The paragenesis of the Inter-lens is broadly consistent with previous studies on the deposit, and consists of albitization; an apatite-calcite-quartz-garnet assemblage; biotite-magnetite ± garnet alteration; K-feldspar ± hornblende alteration; Cu-Au mineralization and post-mineralization alteration and veining. Apatite from the paragenetically early apatite-calcite-quartz-garnet assemblage produce U–Pb ages of 1584 ± 22 Ma and 1587 ± 22 Ma, suggesting that the formation of apatite, and the maximum age of the Inter-lens is synchronous with D2 deformation of the Isan Orogeny and regional peak-metamorphic conditions. Apatite rare earth element-depletion trends display: (1) a depletion in rare earth elements evenly, corresponding with an enrichment in arsenic and (2) a selective light rare earth element depletion. Exposure to an acidic NaCl and/or CaCl2-rich sedimentary-derived fluid is responsible for the selective light rare earth element-depletion trend, while the exposure to a neutral to alkaline S, Na-, and/or Ca-rich magmatic fluid resulted in the depletion of rare earth elements in apatite evenly, while producing an enrichment in arsenic. We suggest the deposit experienced at least two hydrothermal events, with the first event related to peak-metamorphism (~1585 Ma) and a subsequent event related to the emplacement of the nearby (~1530 Ma) Williams–Naraku Batholiths. Brecciation resulted from competency contrasts between ductile metasedimentary rocks of the Inter-lens and surrounding shear zones against the brittle metavolcanic rocks that comprise the ore-bearing breccia, providing permeable pathways for the subsequent ore-bearing fluids.


2015 ◽  
Vol 3 (40) ◽  
pp. 10566-10573 ◽  
Author(s):  
Yufei Hu ◽  
Sabah K. Bux ◽  
Jason H. Grebenkemper ◽  
Susan M. Kauzlarich

ThezTof Yb14MnSb11is improved by the introduction of a light rare earth element, RE3+(RE = Pr, Sm) with partially filled f-levels. The carrier concentration is reduced upon substituting RE3+for Yb2+, adding one electron to the system and improving thezTvalues 30–40% over that of the pristine material.


2011 ◽  
Vol 471 (3-4) ◽  
pp. 66-70 ◽  
Author(s):  
M.R. Koblischka ◽  
A. Koblischka-Veneva ◽  
M. Muralidhar ◽  
Th. Wolf ◽  
N. Hari Babu ◽  
...  

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