Calcul des éléments dipolaires et quadrupolaires de la matrice de transition moléculaire dans Na2
Keyword(s):
In this paper, we study a calculation of the transition elements [Formula: see text] between electronic states of the diatomic molecules Na2. We show the necessary selection rules for the determination of these operators by a method of analytical integration on the variable [Formula: see text], combined with a numerical integration to fifth order. The values found by this simple method of calculation are very reasonable and show that the important transitions [Formula: see text], [Formula: see text]; and [Formula: see text] of the dimer Na2 are dipolar. [Traduit par la revue]
1991 ◽
Vol 433
(1889)
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pp. 547-571
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1992 ◽
Vol 85
(3)
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pp. 541-548
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Keyword(s):
1977 ◽
Vol 12
(1)
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pp. 27-50
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Keyword(s):
1960 ◽
Vol 1
(12)
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pp. 459-460
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