FAST REARRANGEMENT OF exo-NORBORNANOL IN STRONG ACID SOLUTIONS

1965 ◽  
Vol 43 (3) ◽  
pp. 674-678 ◽  
Author(s):  
Gideon Fraenkel ◽  
Phillip D. Ralph ◽  
John P. Kim
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Strong Acid ◽  
Acid Solutions ◽  
Nuclear Magnetic Resonance Spectra ◽  
Strong Acids ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

Nuclear magnetic resonance spectra have been obtained at several temperatures for solutions of 2-exo-norbornanol in strong acids. The spectra change with temperature reversibly. It is concluded that the 2-exo-norbornanol undergoes very rapid rearrangement, the fast steps being 2,6 and 3,2 hydride shifts, respectively.

meso- and dl - .alpha.,.alpha.' -Bis(difluoramino)bibenzyls. Preparation and nuclear magnetic resonance spectra

1967 ◽  
Vol 32 (2) ◽  
pp. 466-468 ◽  
Author(s):  
Frederic Allan Johnson ◽  
Carolyn Haney ◽  
Travis Edward Stevens
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Nuclear Magnetic Resonance Spectra ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic
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