The Formation of Alkenes by the Thermal Elimination Reaction of N-Methyl-4-alkoxypyridinium Iodides. II. An Investigation of the Mechanism
Keyword(s):
A comparison of the products from elimination reactions of a number of compounds containing various leaving groups with those containing the N-methyl oxypyridinium leaving group suggests that the elimination is not occurring by means of a simple E1 mechanism. Changing the anion of the salt from iodide to methyl-sulphate and tetrafluoroborate affects the product composition indicating that the anion is taking part in the reaction. The mechanism of this reaction appears to be on the E1-E2 borderline.
Keyword(s):
1980 ◽
Vol 45
(8)
◽
pp. 2171-2178
2003 ◽
pp. 173-185
2003 ◽
Vol 02
(03)
◽
pp. 357-369
◽
Keyword(s):
2019 ◽
Vol 123
(41)
◽
pp. 8776-8786
1972 ◽
Vol 30
(10)
◽
pp. 894-896
◽