Thiyl Radical Abstraction. A Mechanism for the Free Radical Substitution Reactions of Pentachlorobenzenesulfenyl Chloride
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The substitution reactions of pentachlorobenzenesulfenyl chloride with saturated alkanes were found to proceed by a free radical chain mechanism where the pentachlorobenzenethiyl radical is the predominant chain-carrying species. The selectivity of this radical could be determined by the investigation of the photoinitiated reactions of bispentachlorophenyl disulfide with a number of alkanes.
1980 ◽
Vol 102
(25)
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pp. 7603-7604
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1979 ◽
Vol 101
(8)
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pp. 2239-2240
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Iron-catalysed oxidation of bisulphite aqueous solution: Evidence for a free radical chain mechanism
1994 ◽
Vol 28
(15)
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pp. 2549-2552
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2018 ◽
Vol 155
◽
pp. 012013
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