The intramolecular Diels–Alder reaction: recent advances and synthetic applications
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Recent advances and examples of the intramolecular Diels–Alder reaction are summarized and applications to the total synthesis of natural products, both completed and in progress, noted. A detailed discussion of trienes leading to bicyclo[4.3.0]nonene skeletons is followed by examples of bicyclo[4.4.0]decenes and adducts arising from ortho-quinodimethane precursors. Cycloadditions affording bicyclo[n.4.0] systems and bridged-ring adducts from cyclic dienes conclude this survey which is followed by a discussion of unreactive trienes and a brief analysis of synthetic strategy to complete the review.
1985 ◽
Vol 50
(20)
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pp. 3738-3749
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2013 ◽
Vol 9
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pp. 1414-1418
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2016 ◽
Vol 13
(6)
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pp. 847-860
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