Corroles in 1,3-dipolar cycloaddition reactions

The azomethine ylide generated from the reaction of a corrole-3-carbaldehyde and N-methylglycine was trapped with dimethyl fumarate, dimethyl acetylenedicarboxylate and fullerene C60 in 1,3-dipolar cycloadditions. A similar azomethine ylide generated from a corrole-2-carbaldehyde was trapped with 1,4-naphthoquinone, yielding the expected dehydrogenated 1,3-dipolar cycloadduct and a quinone-fused corrole derivative. A detailed synchrotron single-crystal X-ray diffraction analysis of the gallium(III)(pyridine) complex of 5,10,15-tris(pentafluorophenyl)corrole-3-carbaldehyde is also presented.

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Phenanthridinium-Based Azomethine Ylides in 1,3-Dipolar Cycloaddition with Dimethyl Acetylenedicarboxylate

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19942641 ◽

1994 ◽

Vol 59 (12) ◽

pp. 2641-2649 ◽

Cited By ~ 5

Author(s):

Milan Potáček ◽

Tomáš Topinka ◽

Jiří Dostál ◽

Jaromír Marek

Keyword(s):

Dimethyl Fumarate ◽

Azomethine Ylides ◽

Dipolar Cycloaddition ◽

Dimethyl Acetylenedicarboxylate ◽

X Ray ◽

Dipolar Cycloadditions ◽

Unstable Species

Azomethine ylides generated from 5-(alkoxycarbonylmethyl) phenanthridinium cations I were used in the 1,3-dipolar cycloadditions with dimethyl acetylenedicarboxylate as dipolarophile. The cycloadducts II were found to be very unstable species and readily oxidized to fully aromatic pyrrolo[1,2-f]phenanthridines III. Their structure was compared with the compounds formed by the oxidation of cycloadducts IV of the same ylide with dimethyl fumarate and maleate. In both cases pyrrolines V were found as intermediates. The structure of the products was determined by NMR and MS as well as by X-ray analysis.

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STUDIES ON THE CONFORMATIONS OF 4-N,N-DIMETHYLAMINOTHIANES AND THE CORRESPONDING METHIODIDES. EVIDENCE FROM A SINGLE CRYSTAL X-RAY DIFFRACTION ANALYSIS THAT A TWIST-BOAT CONFORMER EXISTS IN THE SOLID STATE FOR TRIMETHYL-[2,2-DIMETHYL-trans−6-PHENYLTHIAN-r-4-YL]-AMMONIUM IODIDE

Phosphorous and Sulfur and the Related Elements ◽

10.1080/03086648308077555 ◽

1983 ◽

Vol 17 (3) ◽

pp. 343-365 ◽

Cited By ~ 2

Author(s):

Pullachipatti K. Subramanian ◽

Kondareddiar Ramalingam ◽

Nantelle S. Pantaleo ◽

Dick Van Der Helm ◽

Nagichettiar Satyamurthy ◽

...

Keyword(s):

Solid State ◽

Single Crystal ◽

Diffraction Analysis ◽

Ammonium Iodide ◽

X Ray Diffraction ◽

X Ray ◽

Twist Boat

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Synthesis of 4-(3-coumarinyl)-3-benzyl-4-thiazolin-2-one 4-methylbenzylidenehydrazone and determination of the isomeric structure by X-ray analysis

Zeitschrift für Kristallographie - Crystalline Materials ◽

10.1524/zkri.218.12.819.20549 ◽

2003 ◽

Vol 218 (12) ◽

Author(s):

Süheyla Özbey ◽

Nilgün Karalı ◽

Aysel Gürsoy

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

Spectral Data ◽

X Ray Diffraction ◽

X Ray ◽

Isomeric Structure ◽

Elemental Analyses

AbstractIn this study 4-(3-coumarinyl)-3-benzyl-4-thi azolin-2-one 4-methylbenzylidenehydrazone 3 was synthesised. An independent proof of the thiazolylhydrazone structure of 3 was achieved by single crystal X-ray diffraction analysis. Elemental analyses and spectral data (IR,

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Single-crystal X-ray diffraction analysis of nonplanar autoepitaxial silicon layers

Inorganic Materials ◽

10.1134/s0020168509140179 ◽

2009 ◽

Vol 45 (14) ◽

pp. 1610-1613

Author(s):

V. T. Bublik ◽

L. V. Kozhitov ◽

T. T. Kondratenko

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

X Ray Diffraction ◽

X Ray

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Functionalized triphenylphosphine oxide-based manganese(II) complexes for luminescent printing

Dalton Transactions ◽

10.1039/d1dt00914a ◽

2021 ◽

Author(s):

Xiaomeng Huang ◽

Yanyan Qin ◽

Pengfei She ◽

Haixing Meng ◽

Shu-Juan Liu ◽

...

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

Triphenylphosphine Oxide ◽

X Ray Diffraction ◽

X Ray

Three novel neutral manganese(II) complexes (TPhPONMe2)2MnBr2, (TPhPOOMe)2MnBr2, and (TPhPOCF3)2MnBr2 have been designed and synthesized based on functionalized Ph3PO ligand. These structures are clarified by single crystal X-ray diffraction analysis, which...

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A Single Crystal X-Ray Diffraction Analysis of (1R,1′S)-1,1′-Ethylenebis(1,2,3,4-tetrahydro-4,4-dimethyl-1-phenylphosphinolinium) Diperchlorate

ACS Symposium Series - Phosphorus Chemistry ◽

10.1021/bk-1981-0171.ch116 ◽

1981 ◽

pp. 561-565

Author(s):

NARAYANASAMY GURUSAMY ◽

K. DARRELL BERLIN ◽

DICK VAN DER HELM ◽

M. BILAYET HOSSAIN

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

X Ray Diffraction ◽

X Ray

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Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

Beilstein Journal of Organic Chemistry ◽

10.3762/bjoc.12.177 ◽

2016 ◽

Vol 12 ◽

pp. 1877-1883 ◽

Cited By ~ 5

Author(s):

Sambasivarao Kotha ◽

Rama Gunta

Keyword(s):

Single Crystal ◽

Diffraction Analysis ◽

X Ray Diffraction ◽

Ring Closing Metathesis ◽

X Ray ◽

Synthetic Strategy ◽

Norbornene Derivatives

Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.

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