Study of Molecular Structures and Properties of Europium(III) Complexes with Phosphine Oxides by NMR Analysis

2005 ◽  
Vol 44 (6A) ◽  
pp. 3702-3705 ◽  
Author(s):  
Hiroki Iwanaga ◽  
Akio Amano ◽  
Masayuki Oguchi
2006 ◽  
Vol 965 ◽  
Author(s):  
Hiroki Iwanaga ◽  
Fumihiko Aiga ◽  
Akio Amano

ABSTRACTSeveral novel Eu(III) complexes with asymmetric bis-phosphine oxide- ligands were synthesized. The relation between molecular structures of bis-phosphine- oxide ligands and properties of Eu(III) complexes was investigated and some interesting results were obtained. Solubility of Eu(III) complexes in fluorinated medium and silicone oil were strongly dependent on the length of alkyl chain (n) binding two phosphine oxide- parts. Also, the thermal properties of Eu(III) complexes were correlated to the solubility. Eu(III) complex 6(n=3), which has phenyl and n-octyl groups as the substituents of a bis-phosphine oxide- ligand, was found to be highly soluble and have large fluorescence intensity.


2010 ◽  
Vol 63 (11) ◽  
pp. 1951-1959 ◽  
Author(s):  
Bei Liang ◽  
Xiangrong Liu ◽  
Jianjun Chen ◽  
Kanshe Li

2017 ◽  
Vol 172 ◽  
pp. 213-222 ◽  
Author(s):  
Tiparat Tikapunya ◽  
Wei Zou ◽  
Wenwen Yu ◽  
Prudence O. Powell ◽  
Glen P. Fox ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 32 (28) ◽  
pp. no-no
Author(s):  
Atilla Karacar ◽  
Matthias Freytag ◽  
Holger Thoennessen ◽  
Jan Omelanczuk ◽  
Peter G. Jones ◽  
...  

1994 ◽  
Vol 226 (3-4) ◽  
pp. 413-419 ◽  
Author(s):  
Jerzy Lesczyński ◽  
Josef S. Kwiatkowski ◽  
Danuta Leszczyńska ◽  
Brian Hale

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