Kinetics of Hydrogen Evolution at Zero Hydrogen Partial Pressure

1961 ◽  
Vol 108 (4) ◽  
pp. 384 ◽  
Author(s):  
Sigmund Schuldiner



2020 ◽  
Vol 4 (9) ◽  
pp. 4459-4463
Author(s):  
Martijn J. W. Blom ◽  
Wim P. M. van Swaaij ◽  
Guido Mul ◽  
Sascha R. A. Kersten

Control over selectivity towards HCOO− rather than H2 is acquired by using elevated pressure of hydrogen during CO2 electrolysis.



2013 ◽  
Vol 634-638 ◽  
pp. 587-594 ◽  
Author(s):  
Jin Cheng Gao ◽  
Ji Yuan Wang ◽  
Wen Bin Du ◽  
Ling Lin ◽  
Chong Yu Zeng

The effects of temperature and hydrogen partial pressure on 4-Carboxybenzaldehyde (4-CBA) hydrogenation over Pd/TiO2 catalyst were investigated in a batch reactor. The results show that 4-CBA hydrogenation is a consecutive reaction. And 4-CBA hydrogenation to 4-hydroxymethylbenzoic (4-HMBA) is a reversible exothermic reaction. Meanwhile, a parallel reaction of 4-CBA decarbonylation occurs during the process. The hydrogenation rate of 4-HMBA is more sensitive to temperature and hydrogen partial pressure than that of 4-CBA. Macro-kinetics of 4-CBA reaction over Pd/TiO2 was obtained from the experimental data using the power-law kinetics model. The apparent activation energies of 4-CBA hydrogenation, 4-HMBA hydrogenation, 4-CBA decarbonylation and 4-HMBA dehydrogenation are 29.65 kJ/mol, 42.55 kJ/mol, 74.32 kJ/mol and 69.34 kJ/mol, respectively. The reaction orders with respect to 4-CBA and 4-HMBA are both first-order.



2010 ◽  
Vol 31 (2) ◽  
pp. 205-212
Author(s):  
Hong WANG ◽  
Yong YANG ◽  
Baoshan WU ◽  
Jian XU ◽  
Hulin WANG ◽  
...  




2010 ◽  
Vol 24 (2) ◽  
pp. 772-784 ◽  
Author(s):  
M. Mapiour ◽  
V. Sundaramurthy ◽  
A. K. Dalai ◽  
J. Adjaye




Author(s):  
Vasant R. Choudhary ◽  
Sudhakar K. Chaudhari


Sign in / Sign up

Export Citation Format

Share Document