scholarly journals Development of YDB/GDC Composite Electrolyte For Low-Temperature Solid Oxide Fuel Cells

2005 ◽  
Vol 2005-07 (1) ◽  
pp. 1110-1116 ◽  
Author(s):  
Y. J. Leng
2020 ◽  
Vol 10 (11) ◽  
pp. 3761
Author(s):  
Muhammed Ali S.A. ◽  
Jarot Raharjo ◽  
Mustafa Anwar ◽  
Deni Shidqi Khaerudini ◽  
Andanastuti Muchtar ◽  
...  

Perovskite-based composite cathodes, La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF)–Ce0.8Sm0.2O1.9-carbonate (SDCC), were investigated as cathode materials for low-temperature solid-oxide fuel cells. The LSCF was mixed with the SDC–carbonate (SDCC) composite electrolyte at different weight percentages (i.e., 30, 40, and 50 wt %) to prepare the LSCF–SDCC composite cathode. The effect of SDCC composite electrolyte content on the diffraction pattern, microstructure, specific surface area, and electrochemical performances of the LSCF–SDCC composite cathode were evaluated. The XRD pattern revealed that the SDCC phase diffraction peaks vary according to its increasing addition to the system. The introduction of SDCCs within the composite cathode did not change the LSCF phase structure and its specific surface area. However, the electrical performance of the realized cell drastically changed with the increase of the SDCC content in the LSCF microstructure. This drastic change can be ascribed to the poor in-plane electronic conduction at the surface of the LSCF cathode layer due to the presence of the insulating phase of SDC and molten carbonate. Among the cathodes investigated, LSCF–30SDCC showed the best cell performance, exhibiting a power density value of 60.3–75.4 mW/cm2 at 600 °C to 650 °C.


2018 ◽  
Vol 10 (1) ◽  
pp. 806-818 ◽  
Author(s):  
Amjad Ali ◽  
Asia Rafique ◽  
Muhammad Kaleemullah ◽  
Ghazanfar Abbas ◽  
M. Ajmal Khan ◽  
...  

2009 ◽  
Vol 33 (13) ◽  
pp. 1138-1144 ◽  
Author(s):  
Zhan Gao ◽  
Zongqiang Mao ◽  
Cheng Wang ◽  
Jianbing Huang ◽  
Zhixiang Liu

2019 ◽  
Vol 44 (26) ◽  
pp. 13843-13851 ◽  
Author(s):  
Zuying Feng ◽  
Liang Liu ◽  
Lingyao Li ◽  
Jiahe Chen ◽  
Yuhong Liu ◽  
...  

2010 ◽  
Vol 105-106 ◽  
pp. 687-690 ◽  
Author(s):  
Jing Di ◽  
Ming Ming Chen ◽  
Cheng Yang Wang ◽  
Jia Ming Zheng ◽  
Bin Zhu

Composites consisting of Ce0.8Sm0.2O1.9 (SDC)-carbonate were developed as electrolytes for low temperature solid oxide fuel cells (LTSOFC). The SDC power was prepared by sol-gel method. The carbonates were binary eutectics of (Li/Na)2CO3, (Li/K)2CO3 and (K/Na)2CO3. Conductivity measurements showed that the conductivities were depended on the type of carbonates. Discontinuities were found in the Arrhenius plots for both SDC-(Li/Na)2CO3 and SDC-(Li/K)2CO3. For SDC-(Na/K)2CO3 composite electrolyte, the conductivity increased as temperature rose following one slope. Single cells based on various composites were fabricated by a uniaxial die-press method and tested at 450-600 oC. The results showed all cells exhibited improved performances upon that of pure SDC-based cell. The best power density of 532 mW cm-2 at 600 oC was achieved for LTSOFC using composite of SDC and (Li/Na)2CO3. Conductivity mechanism was also discussed.


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