Electrochemical Behavior and Solvation Analysis of Rare Earth Complexes in Ionic Liquids Media Investigated by SECM and Raman Spectroscopy

2016 ◽  
Vol 45 (37) ◽  
pp. 14634-14644 ◽  
Author(s):  
Megan E. Fieser ◽  
David H. Woen ◽  
Jordan F. Corbey ◽  
Thomas J. Mueller ◽  
Joseph W. Ziller ◽  
...  

Raman spectra have been collected on single crystals of over 20 different rare earth complexes containing reduced dinitrogen ligands to determine if these data will correlate with periodic properties or relative stability.


2021 ◽  
Author(s):  
Andreas Schnepf ◽  
Svetlana Klementyeva ◽  
Claudio Schrenk ◽  
Marat M Khusniyarov ◽  
Minghui Zhang

We report the synthesis, structure and magnetic properties of the first rare earth complexes of metalloid group 14 clusters [(thf)2Ln(Ge9Hyp3)2] (Ln = Eu, Sm, Hyp = Si(SiMe3)3). X-ray crystallographic analysis...


Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115057
Author(s):  
Katarzyna Wolska ◽  
Jan Janczak ◽  
Paula Gawryszewska ◽  
Jerzy Lisowski

2021 ◽  
pp. 120516
Author(s):  
Renan Barrach Guerra ◽  
Diogo Alves Gálico ◽  
Thais Fernanda de Campos Fraga-Silva ◽  
Julia Aguiar ◽  
James Venturini ◽  
...  

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Dong Uk Lee ◽  
Jin Yeong Jeong ◽  
Ji Woong Han ◽  
Gi-Chung Kwon ◽  
Pankaj Attri ◽  
...  

Conducting polymer has many applications in electronics, optical devices, sensors, and so on; however, there is still a massive scope of improvement in this area. Therefore, towards this aim, in this study, we synthesized a new thiophene-based conducting polymer, 2-heptadecyl-5-hexyl-6-(5-methylthiophen-2-yl)-4-(5-((E)-prop-1-enyl)thiophen-2-yl)-5H-pyrrolo[3,4-d]thiazole (HHMPT). Further, to increase its application, the interactions between the conducting polymer (HHMPT) and ionic liquids (ILs) were investigated by UV-Vis spectroscopy, FTIR spectroscopy, and confocal Raman spectroscopy techniques. Moreover, film roughness and conductivity of the polymer film with or without ILs were also studied. The imidazolium- and ammonium family ILs with the potential to interact with the newly synthesized conducting polymer were used. The results of the interaction studies revealed that the imidazolium family IL-polymer mixtures and ammonium family IL-polymer mixtures have almost similar conductivity at low concentration of ILs. This study provides an insight into the combined effect of a polymer and ILs and may generate many theoretical and experimental opportunities.


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