scholarly journals Proton-Coupled-Electron Transfer Enhances the Electrocatalytic Reduction of Nitrite to NO in a Bioinspired Copper Complex

2019 ◽  
Keyword(s):  
Electron Transfer ◽  
Copper Complex ◽  
Electrocatalytic Reduction ◽  
Proton Coupled Electron Transfer

scholarly journals Proton-Coupled Electron Transfer Enhances the Electrocatalytic Reduction of Nitrite to NO in a Bioinspired Copper Complex

ACS Catalysis ◽  
2018 ◽  
Vol 8 (6) ◽  
pp. 5070-5084 ◽  
Author(s):  
Giacomo Cioncoloni ◽  
Isolda Roger ◽  
Paul S. Wheatley ◽  
Claire Wilson ◽  
Russell E. Morris ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Copper Complex ◽  
Electrocatalytic Reduction ◽  
Proton Coupled Electron Transfer

scholarly journals Proton-coupled electron transfer in the electrocatalysis of CO2 reduction: prediction of sequential vs. concerted pathways using DFT

2017 ◽  
Vol 8 (1) ◽  
pp. 458-465 ◽  
Author(s):  
Adrien J. Göttle ◽  
Marc T. M. Koper
Keyword(s):  
Electron Transfer ◽  
Co2 Reduction ◽  
Electrocatalytic Reduction ◽  
Cobalt Porphyrin ◽  
Proton Coupled Electron Transfer ◽  
Detailed Picture

We provide a complete and computationally detailed picture of the mechanism of the initial stages of the electrocatalytic reduction of CO2 in water catalysed by cobalt porphyrin complexes.

Proton-coupled electron transfer in the reduction of diiron hexacarbonyl complexes and its enhancement on the electrocatalytic reduction of protons by a pendant basic group

2019 ◽  
Vol 48 (36) ◽  
pp. 13711-13718 ◽  
Author(s):  
Wei Zhong ◽  
Li Wu ◽  
Weidong Jiang ◽  
Yulong Li ◽  
Natarajan Mookan ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electrocatalytic Reduction ◽  
Proton Reduction ◽  
Basic Group ◽  
Proton Coupled Electron Transfer ◽  
Proton Relay ◽  
Kinetic Resistance

The pendant basic groups in a diiron complex acted as proton relay to ease the kinetic resistance in proton reduction and enhance proton-coupled electron transfer (PCET).

scholarly journals Electrochemical water oxidation using a copper complex

2018 ◽  
Vol 47 (31) ◽  
pp. 10737-10741 ◽  
Author(s):  
Sebastian Nestke ◽  
Emanuel Ronge ◽  
Inke Siewert
Keyword(s):  
Electron Transfer ◽  
Copper Complex ◽  
Water Oxidation ◽  
Oxidation Catalysis ◽  
Proton Coupled Electron Transfer ◽  
Water Oxidation Catalysis

This study highlights the importance of proton coupled electron transfer (PCET) during electrochemical-driven water oxidation catalysis employing a copper complex.

scholarly journals Electron–Nuclear Dynamics Accompanying Proton-Coupled Electron Transfer

2021 ◽  
Vol 143 (8) ◽  
pp. 3104-3112
Author(s):  
Yusuke Yoneda ◽  
S. Jimena Mora ◽  
James Shee ◽  
Brian L. Wadsworth ◽  
Eric A. Arsenault ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Nuclear Dynamics ◽  
Proton Coupled Electron Transfer

Facile proton-coupled electron transfer enabled by coordination-induced E–H bond weakening to boron

2021 ◽  
Author(s):  
Anthony Wong ◽  
Arunavo Chakraborty ◽  
Deependra Bawari ◽  
Guang Wu ◽  
Roman Dobrovetsky ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Proton Coupled Electron Transfer

Coordination induced bond weakening (CIBW) leads to facile PCET at various E–H bonds.

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