scholarly journals On a Conjecture regarding Fisher Information

2015 ◽  
Vol 2015 ◽  
pp. 1-4 ◽  
Author(s):  
Angelo Plastino ◽  
Guido Bellomo ◽  
Angel Ricardo Plastino

Fisher’s information measureIplays a very important role in diverse areas of theoretical physics. The associated measuresIxandIp, as functionals of quantum probability distributions defined in, respectively, coordinate and momentum spaces, are the protagonists of our present considerations. The productIxIphas been conjectured to exhibit a nontrivial lower bound in Hall (2000). More explicitly, this conjecture says that for any pure state of a particle in one dimensionIxIp≥4. We show here that such is not the case. This is illustrated, in particular, for pure states that are solutions to the free-particle Schrödinger equation. In fact, we construct a family of counterexamples to the conjecture, corresponding to time-dependent solutions of the free-particle Schrödinger equation. We also conjecture that any normalizable time-dependent solution of this equation verifiesIxIp→0fort→∞.

1999 ◽  
Vol 31 (3) ◽  
pp. 379-382
Author(s):  
Li Bozang ◽  
Wang Shi'en ◽  
Zhang Lingyun ◽  
Zhang Xiangdong

2003 ◽  
Vol 94 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Ravi K. Vadapalli ◽  
Charles A. Weatherford ◽  
Ioana Banicescu ◽  
Ricolindo L. Cariño ◽  
Jianping Zhu

Author(s):  
Niels Engholm Henriksen ◽  
Flemming Yssing Hansen

This introductory chapter considers first the relation between molecular reaction dynamics and the major branches of physical chemistry. The concept of elementary chemical reactions at the quantized state-to-state level is discussed. The theoretical description of these reactions based on the time-dependent Schrödinger equation and the Born–Oppenheimer approximation is introduced and the resulting time-dependent Schrödinger equation describing the nuclear dynamics is discussed. The chapter concludes with a brief discussion of matter at thermal equilibrium, focusing at the Boltzmann distribution. Thus, the Boltzmann distribution for vibrational, rotational, and translational degrees of freedom is discussed and illustrated.


Author(s):  
Frank S. Levin

Chapter 7 illustrates the results obtained by applying the Schrödinger equation to a simple pedagogical quantum system, the particle in a one-dimensional box. The wave functions are seen to be sine waves; their wavelengths are evaluated and used to calculate the quantized energies via the de Broglie relation. An energy-level diagram of some of the energies is constructed; on it are illustrations of the corresponding wave functions and probability distributions. The wave functions are seen to be either symmetric or antisymmetric about the midpoint of the line representing the box, thereby providing a lead-in to the later exploration of certain symmetry properties of multi-electron atoms. It is next pointed out that the Schrödinger equation for this system is identical to Newton’s equation describing the vibrations of a stretched musical string. The different meaning of the two solutions is discussed, as is the concept and structure of linear superpositions of them.


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