Piscicartone, a Rotenoid From Piscidia carthagenensis
Keyword(s):
The bark of the roots of Piscidia carthagenensis afforded the known insecticides rotenone (1) and millettone (2), as well as the new rotenoid piscicartone (3). The structure of 3 followed from nuclear magnetic resonance studies, while its absolute configuration (AC) was determined by vibrational circular dichroism (VCD) measurements in comparison with discrete Fourier transform B3LYP/DGDZVPcalculated spectra using the Compare VOA software. In addition, the AC of 1 and 2 was verified using the same VCD methodology.
1997 ◽
Vol 272
(12)
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pp. 7639-7645
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1993 ◽
Vol 41
(2)
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pp. 157-161
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2004 ◽
Vol 60
(13)
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pp. 2985-2992
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