Decay resistance of acetic anhydride modified wood: a review

2013 ◽  
Vol 4 (3) ◽  
pp. 137-143 ◽  
Author(s):  
G Alfredsen ◽  
P O Flæte ◽  
H Militz
Holzforschung ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Lukas Emmerich ◽  
Maja Bleckmann ◽  
Sarah Strohbusch ◽  
Christian Brischke ◽  
Susanne Bollmus ◽  
...  

Abstract Chemical wood modification has been used to modify wood and improve its decay resistance. However, the mode of protective action is still not fully understood. Occasionally, outdoor products made from chemically modified timber (CMT) show internal decay while their outer shell remains intact. Hence, it was hypothesized that wood decay fungi may grow through CMT without losing their capability to degrade non-modified wood. This study aimed at developing a laboratory test set-up to investigate (1) whether decay fungi grow through CMT and (2) retain their ability to degrade non-modified wood. Acetylated and 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU) treated wood were used in decay tests with modified ‘mantle specimens’ and untreated ‘core dowels’. It became evident that white rot (Trametes versicolor), brown rot (Coniophora puteana) and soft rot fungi can grow through CMT without losing their ability to degrade untreated wood. Consequently, full volume impregnation of wood with the modifying agent is required to achieve complete protection of wooden products. In decay tests with DMDHEU treated specimens, significant amounts of apparently non-fixated DMDHEU were translocated from modified mantle specimens to untreated wood cores. A diffusion-driven transport of nitrogen and DMDHEU seemed to be responsible for mass translocation during decay testing.


Forests ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1462
Author(s):  
Ján Iždinský ◽  
Zuzana Vidholdová ◽  
Ladislav Reinprecht

In recent years, the production and consumption of thermally modified wood (TMW) has been increasing. Offcuts and other waste generated during TMWs processing into products, as well as already disposed products based on TMWs can be an input recycled raw material for production of particleboards (PBs). In a laboratory, 16 mm thick 3-layer PBs bonded with urea-formaldehyde (UF) resin were produced at 5.8 MPa, 240 °C and 8 s pressing factor. In PBs, the particles from fresh spruce wood and mixed particles from offcuts of pine, beech, and ash TMWs were combined in weight ratios of 100:0, 80:20, 50:50 and 0:100. Thickness swelling (TS) and water absorption (WA) of PBs decreased with increased portion of TMW particles, i.e., TS after 24 h maximally about 72.3% and WA after 24 h maximally about 64%. However, mechanical properties of PBs worsened proportionally with a higher content of recycled TMW—apparently, the modulus of rupture (MOR) up to 55.5% and internal bond (IB) up to 46.2%, while negative effect of TMW particles on the modulus of elasticity (MOE) was milder. Decay resistance of PBs to the brown-rot fungus Serpula lacrymans (Schumacher ex Fries) S.F.Gray increased if they contained TMW particles, maximally about 45%, while the mould resistance of PBs containing TMW particles improved only in the first days of test. In summary, the recycled TMW particles can improve the decay and water resistance of PBs exposed to higher humidity environment. However, worsening of their mechanical properties could appear, as well.


2008 ◽  
Vol 62 (4) ◽  
pp. 448-454 ◽  
Author(s):  
Cláudio Henrique Soares Del Menezzi ◽  
Raiana Quirino de Souza ◽  
Robert Morais Thompson ◽  
Divino Eterno Teixeira ◽  
Esmeralda Yoshico Arakaki Okino ◽  
...  

Holzforschung ◽  
2014 ◽  
Vol 68 (2) ◽  
pp. 239-246 ◽  
Author(s):  
Rebecka Ringman ◽  
Annica Pilgård ◽  
Christian Brischke ◽  
Klaus Richter

Abstract Chemically or physically modified wood materials have enhanced resistance to wood decay fungi. In contrast to treatments with traditional wood preservatives, where the resistance is caused mainly by the toxicity of the chemicals added, little is known about the mode of action of nontoxic wood modification methods. This study reviews established theories related to resistance in acetylated, furfurylated, dimethylol dihydroxyethyleneurea-treated, and thermally modified wood. The main conclusion is that only one theory provides a consistent explanation for the initial inhibition of brown rot degradation in modified wood, that is, moisture exclusion via the reduction of cell wall voids. Other proposed mechanisms, such as enzyme nonrecognition, micropore blocking, and reducing the number of free hydroxyl groups, may reduce the degradation rate when cell wall water uptake is no longer impeded.


2005 ◽  
Vol 55 (1) ◽  
pp. 69-76 ◽  
Author(s):  
C.A.S. Hill ◽  
S.C. Forster ◽  
M.R.M. Farahani ◽  
M.D.C. Hale ◽  
G.A. Ormondroyd ◽  
...  

BioResources ◽  
2006 ◽  
Vol 1 (1) ◽  
pp. 67-74

The purpose of this paper is to show the effects of level of substitution with a linear chain anhydride (propionic anhydride) on decay resistance and on water vapour sorption of modified Scots pine sapwood. The work described herein has demonstrated that chemically modified Scots pine sapwood with propionic anhydride afforded substantial bioprotection against Coniophora puteana . It required a weight gain of approximately 17% following reaction to ensure complete protection. The sorption of water vapour of propionic anhydride modified wood was greatly reduced.


2006 ◽  
Vol 57 (1) ◽  
pp. 57-62 ◽  
Author(s):  
Naoto Habu ◽  
Yoko Nagasawa ◽  
Masahiro Samejima ◽  
Tomoko M. Nakanishi

2016 ◽  
Vol 7 (2) ◽  
pp. 66-70 ◽  
Author(s):  
S. L. Zelinka ◽  
R. Ringman ◽  
A. Pilgård ◽  
E. E. Thybring ◽  
J. E. Jakes ◽  
...  

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