The influence of aluminium substitution and crystallinity on the Mössbauer spectra of goethite
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AbstractBoth aluminium substitution and poor crystallinity reduce the magnetic hyperfine field of goethite. Mössbauer spectra taken at 4·2 K show that the effect of poor crystallinity is similar to that of Al substitution, i.e. it reduces the saturation hyperfine field. A multiple correlation was found to exist between the magnetic hyperfine field at 4·2 K as a dependent variable vs Al substitution and crystallinity as independent variables. If a hyperfine field is to be interpreted with respect to either Al substitution or crystallinity, it is therefore necessary to have knowledge of the other variable.
1984 ◽
Vol 6
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pp. 1047-1052
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2010 ◽
Vol 322
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pp. 3841-3850
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1974 ◽
Vol 267
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pp. 299-304
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2015 ◽
Vol 384
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pp. 284-288
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2009 ◽
Vol 488
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pp. 18-22
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