Establishing effective network manufacturing alliance is the top priority of carrying out network manufacturing. Under circumstance of realizing resource sharing in network manufacturing, a method of network manufacturing alliance establishing based on service resource matching is put forward. Based on model of resource description framework, manufacturing service resource description model and matching strategy are established. According to describing feature of resource properties, matching of manufacturing resource and service resource is further transferred into corresponding qualitative and quantitative matching, similarity measuring methods of qualitative and quantitative properties in the matching process are presented respectively so as to accurately evaluate matching degree between manufacturing resource and service request. Availability of the model and its matching algorithm is verified by means of practical instances.