scholarly journals Development of Functional Materials via Polymer Encapsulation into Metal–Organic Frameworks

Author(s):  
Nobuhiko Hosono ◽  
Takashi Uemura
Author(s):  
Peiyu Cai ◽  
Wenmiao Chen ◽  
Gregory S. Day ◽  
Hannah F. Drake ◽  
Elizabeth A. Joseph ◽  
...  

2017 ◽  
Vol 53 (7) ◽  
pp. 1249-1252 ◽  
Author(s):  
Kang Liang ◽  
Ru Wang ◽  
Manon Boutter ◽  
Cara M. Doherty ◽  
Xavier Mulet ◽  
...  

Biomimetic mineralization exploits natural biomineralization processes for the design and fabrication of synthetic functional materials.


2021 ◽  
Author(s):  
Adam Sapnik ◽  
Christopher W. Ashling ◽  
Lauren K. Macreadie ◽  
Seok J. Lee ◽  
Tim Johnson ◽  
...  

<div><p>Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas adsorption in the topologically disordered Fe-BTC framework and its crystalline counterpart, MIL‑100. Despite their similar chemistry and local structure, they exhibit very different sorption behaviour towards a range of industrial gases, noble gases and hydrocarbons. Virial analysis reveals that Fe-BTC has enhanced interaction strength with guest molecules compared to MIL‑100. Most notably, we observe striking discrimination between the adsorption of C<sub>3</sub>H<sub>6</sub> and C<sub>3</sub>H<sub>8</sub> in Fe‑BTC, with over a twofold increase in the amount of C<sub>3</sub>H<sub>6</sub> being adsorbed than C<sub>3</sub>H<sub>8</sub>. Thermodynamic selectivity towards a range of industrially relevant binary mixtures is probed using ideal adsorbed solution theory (IAST). Together, this suggests the disordered material may possess powerful separation capabilities that are rare even amongst crystalline frameworks.</p></div>


ChemInform ◽  
2012 ◽  
Vol 43 (26) ◽  
pp. no-no
Author(s):  
Pounraj Thanasekaran ◽  
Tzuoo-Tsair Luo ◽  
Jing-Yun Wu ◽  
Kuang-Lieh Lu

Author(s):  
Adam Sapnik ◽  
Christopher W. Ashling ◽  
Lauren Macreadie ◽  
Seok J. Lee ◽  
Timothy Johnson ◽  
...  

Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas...


2012 ◽  
Vol 41 (18) ◽  
pp. 5437 ◽  
Author(s):  
Pounraj Thanasekaran ◽  
Tzuoo-Tsair Luo ◽  
Jing-Yun Wu ◽  
Kuang-Lieh Lu

CrystEngComm ◽  
2021 ◽  
Author(s):  
Hong Ou ◽  
Qiongyi Xie ◽  
Qingyun Yang ◽  
Jianen Zhou ◽  
Akif Zeb ◽  
...  

In recent years, metal-organic frameworks (MOFs) have been widely used in various fields, especially electrochemical energy storage and conversion area, because of their excellent properties. It is reported that the...


Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 691 ◽  
Author(s):  
Chi-Xuan Yao ◽  
Ning Zhao ◽  
Ji-Chao Liu ◽  
Li-Jun Chen ◽  
Jing-Min Liu ◽  
...  

The high speed of contaminants growth needs the burgeoning of new analytical techniques to keep up with the continuous demand for monitoring and legislation on food safety and environmental pollution control. Metal-organic frameworks (MOFs) are a kind of advanced crystal porous materials with controllable apertures, which are self-assembled by organic ligands and inorganic metal nodes. They have the merits of large specific surface areas, high porosity and the diversity of structures and functions. Latterly, the utilization of metal-organic frameworks has attracted much attention in environmental protection and the food industry. MOFs have exhibited great value as sensing materials for many targets. Among many sensing methods, fluorometric sensing is one of the widely studied methods in the detection of harmful substances in food and environmental samples. Fluorometric detection based on MOFs and its functional materials is currently one of the most key research subjects in the food and environmental fields. It has gradually become a hot research direction to construct the highly sensitive rapid sensors to detect harmful substances in the food matrix based on metal-organic frameworks. In this paper, we introduced the synthesis and detection application characteristics (absorption, fluorescence, etc.) of metal-organic frameworks. We summarized their applications in the MOFs-based fluorometric detection of harmful substances in food and water over the past few years. The harmful substances mainly include heavy metals, organic pollutants and other small molecules, etc. On this basis, the future development and possible application of the MOFs have prospected in this review paper.


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