scholarly journals The Kinetics of the Chromic Acid Oxidation of Phenylphosphonous Acid

1970 ◽  
Vol 43 (3) ◽  
pp. 590-594 ◽  
Author(s):  
Kalyan K. Sen Gupta
Tetrahedron ◽  
1960 ◽  
Vol 8 (3-4) ◽  
pp. 313-335 ◽  
Author(s):  
K.B. Wiberg ◽  
R.J. Evans

1970 ◽  
Vol 43 (12) ◽  
pp. 3841-3845 ◽  
Author(s):  
Kalyan K. Sengupta ◽  
A. K. Chatterjee ◽  
S. P. Moulik

1968 ◽  
Vol 46 (3) ◽  
pp. 441-449 ◽  
Author(s):  
Donald G. Lee ◽  
William L. Downey ◽  
R. Michael Maass

The rate law for oxidation of 2-propanol by chromic acid in aqueous acetone solutions has been found to be V = k3 [Cr(VI)| [2-propanol]ho, with the magnitude of k3 being over 700 times as great in 93.3% acetone as it is in water. In other respects (primary deuterium isotope effect, Hammett "rho" value, and salt effects) the general features of the reaction strongly resemble those observed in aqueous acetic acid solutions.


1958 ◽  
Vol 80 (12) ◽  
pp. 3030-3033 ◽  
Author(s):  
George T. E. Graham ◽  
F. H. Westheimer

1971 ◽  
Vol 92 (1) ◽  
pp. 51-55 ◽  
Author(s):  
Kousaburo OHASHI ◽  
Atsushi OHNUMA ◽  
Kastsumi YAMAMOTO ◽  
Yoshimi KURIMURA

1958 ◽  
Vol 80 (12) ◽  
pp. 3022-3029 ◽  
Author(s):  
Kenneth B. Wiberg ◽  
Theodore Mill

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