The Kinetics of the Chromic Acid Oxidation of Isopropyl Alcohol: The Induced Oxidation of Manganous Ion

1949 ◽  
Vol 17 (1) ◽  
pp. 61-70 ◽  
Author(s):  
Warren Watanabe ◽  
F. H. Westheimer
Tetrahedron ◽  
1960 ◽  
Vol 8 (3-4) ◽  
pp. 313-335 ◽  
Author(s):  
K.B. Wiberg ◽  
R.J. Evans

1970 ◽  
Vol 43 (12) ◽  
pp. 3841-3845 ◽  
Author(s):  
Kalyan K. Sengupta ◽  
A. K. Chatterjee ◽  
S. P. Moulik

1968 ◽  
Vol 46 (3) ◽  
pp. 441-449 ◽  
Author(s):  
Donald G. Lee ◽  
William L. Downey ◽  
R. Michael Maass

The rate law for oxidation of 2-propanol by chromic acid in aqueous acetone solutions has been found to be V = k3 [Cr(VI)| [2-propanol]ho, with the magnitude of k3 being over 700 times as great in 93.3% acetone as it is in water. In other respects (primary deuterium isotope effect, Hammett "rho" value, and salt effects) the general features of the reaction strongly resemble those observed in aqueous acetic acid solutions.


1958 ◽  
Vol 80 (12) ◽  
pp. 3030-3033 ◽  
Author(s):  
George T. E. Graham ◽  
F. H. Westheimer

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