scholarly journals Direct Evidence for the Peroxo Substitution of the Oxo Group in the Oxotitanium(IV) Porphyrin Complex in the Aqueous Solution

1986 ◽  
Vol 59 (8) ◽  
pp. 2629-2630 ◽  
Author(s):  
Masahiko Inamo ◽  
Shigenobu Funahashi ◽  
Motoharu Tanaka
Keyword(s):  
Aqueous Solution ◽  
Direct Evidence ◽  
Porphyrin Complex

Direct Evidence on the Existence of [Mo132] Keplerate-Type Species in Aqueous Solution†

2007 ◽  
Vol 46 (21) ◽  
pp. 8469-8471 ◽  
Author(s):  
Soumyajit Roy ◽  
Karel L. Planken ◽  
Robbert Kim ◽  
Dexx v. d. Mandele ◽  
Willem K. Kegel
Keyword(s):  
Aqueous Solution ◽  
Type Species ◽  
Direct Evidence

scholarly journals Direct Evidence on the Existence of [Mo132] Keplerate-Type Species in Aqueous Solution

2010 ◽  
Vol 49 (12) ◽  
pp. 5775-5775 ◽  
Author(s):  
Soumyajit Roy ◽  
Karel L. Planken ◽  
Robbert Kim ◽  
Dexx v. d. Mandele ◽  
Willem K. Kegel
Keyword(s):  
Aqueous Solution ◽  
Type Species ◽  
Direct Evidence

scholarly journals Efficient bulk mass accommodation of N<sub>2</sub>O<sub>5</sub> into neutral aqueous aerosol

2016 ◽  
Author(s):  
Goran Gržinić ◽  
Thorsten Bartels-Rausch ◽  
Andreas Türler ◽  
Markus Ammann
Keyword(s):  
Aqueous Solution ◽  
Isotope Exchange ◽  
Room Temperature ◽  
Direct Evidence ◽  
Aerosol Particles ◽  
Radioactive Tracer ◽  
Accommodation Coefficient ◽  
Bulk Mass

Abstract. An isotope exchange experiment with the short-lived radioactive tracer 13N is used to trace N2O5 uptake into nitrate containing aqueous aerosol particles. While uptake of 13N labelled N2O5 to deliquesced Na2SO4 aerosol is consistent with previous studies, in presence of aerosol phase nitrate efficient exchange of labeled nitrate with the non-labeled nitrate pool was observed. The experiments provide direct evidence for efficient bulk mass accommodation of N2O5 into aqueous solution with an accommodation coefficient >0.4 at room temperature, as well as for the fast disproportionation into nitronium and nitrate. While for experimental reasons this study is limited to non-acidic aerosol, it is likely that mass accommodation is not limiting N2O5 uptake also under wider ranges of conditions.

First Direct Evidence for Stereospecific Olefin Epoxidation and Alkane Hydroxylation by an Oxoiron(IV) Porphyrin Complex

2003 ◽  
Vol 125 (48) ◽  
pp. 14674-14675 ◽  
Author(s):  
Wonwoo Nam ◽  
Se-Eun Park ◽  
In Kyung Lim ◽  
Mi Hee Lim ◽  
Jongki Hong ◽  
...  
Keyword(s):  
Direct Evidence ◽  
Olefin Epoxidation ◽  
Porphyrin Complex ◽  
Alkane Hydroxylation

The direct evidence for ESPT route and ICT emission of N6-Methyladenine in aqueous solution

2021 ◽  
Vol 229 ◽  
pp. 117698 ◽  
Author(s):  
Yunfan Yang ◽  
Wei Shi ◽  
Yunpeng Chen ◽  
Fengcai Ma ◽  
Yongqing Li
Keyword(s):  
Aqueous Solution ◽  
Direct Evidence
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