scholarly journals Co-loading of Pt and Fe on *BEA Zeolite for Enhanced Isomerization Selectivity in n-Heptane Conversion

2018 ◽  
Vol 47 (11) ◽  
pp. 1428-1430
Author(s):  
Ryosuke Ushiki ◽  
Yoshinori Akada ◽  
Masahiko Matsukata
BMC Chemistry ◽  
2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Z. Ghaderi ◽  
M. H. Peyrovi ◽  
N. Parsafard

AbstractPt loaded on a series of MCM-48 silica and composites with HZSM-5 zeolite, HY zeolite, or TiO2 has been prepared and studied for n-heptane isomerization reaction at 200–350 °C. The structural characterization, acid distribution, and morphology of these catalysts were characterized by X-ray diffraction, Fourier transform infrared, UV–Vis diffuse reflectance, scanning electron microscope, temperature-programmed desorption of NH3, and nitrogen adsorption–desorption methods. The results show that these catalysts have a good selectivity to multi branched isomers, while producing low aromatic compounds. Also, these new composite catalysts prove the catalytic stability during the time of reaction. The most desirable results, and significantly higher n-heptane conversion and isomerization selectivity were achieved with Pt/MCM48-HZSM5 catalyst.


2017 ◽  
Vol 68 (1) ◽  
pp. 116-120
Author(s):  
Iuliean Vasile Asaftei ◽  
Neculai Catalin Lungu ◽  
Lucian Mihail Birsa ◽  
Ioan Gabriel Sandu ◽  
Laura Gabriela Sarbu ◽  
...  

The conversion of n-heptanes into aromatic hydrocarbons benzene, toluene and xylenes (BTX), by the chromatographic pulse method in the temperature range of 673 - 823K was performed over the HZSM-5 and Ag-HZSM-5 zeolites modified by ion exchange with AgNO3 aqueous solutions. The catalysts, HZSM-5 (SiO2/Al2O3 = 33.9), and Ag-HZSM-5 (Ag1-HZSM-5 wt. % Ag1.02, Ag2-HZSM-5 wt. % Ag 1.62; and Ag3-HZSM-5 wt. % Ag 2.05 having different acid strength distribution exhibit a conversion and a yield of aromatics depending on temperature and metal content. The yield of aromatic hydrocarbons BTX appreciably increased by incorporating silver cations Ag+ into HZSM-5.


2021 ◽  
Vol 412 ◽  
pp. 128566
Author(s):  
Umer Khalil ◽  
Zhendong Liu ◽  
Ce Peng ◽  
Naomichi Hikichi ◽  
Toru Wakihara ◽  
...  

2021 ◽  
Vol 287 ◽  
pp. 119951
Author(s):  
Eunhee Jang ◽  
Layoung Choi ◽  
Jinseong Kim ◽  
Yanghwan Jeong ◽  
Hionsuck Baik ◽  
...  

2009 ◽  
Vol 142 (3-4) ◽  
pp. 185-191 ◽  
Author(s):  
S. Dzwigaj ◽  
E. Ivanova ◽  
R. Kefirov ◽  
K. Hadjiivanov ◽  
F. Averseng ◽  
...  

2016 ◽  
Vol 336 ◽  
pp. 1-10 ◽  
Author(s):  
A. Astafan ◽  
M.A. Benghalem ◽  
Y. Pouilloux ◽  
J. Patarin ◽  
N. Bats ◽  
...  
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