AbstractPollen assemblage changes and stable hydrogen isotope analysis of mosses (Sphagnum magellanicum and Drepanocladus s.l.) from a bog in Tierra del Fuego, Argentina, provided independent proxies for reconstructing changes in effective moisture and temperature over the past 16,000 cal yr B.P. A deterministic model was used to reconstruct the stable hydrogen isotope composition of meteoric water from the D/H ratios of bog mosses over the last 16,000 years. Abrupt changes in temperature, as recorded in D/H ratios of moss cellulose, were accompanied by synchronous changes in vegetation composition during the late Pleistocene and early and middle Holocene, when moisture levels were lower than today. In contrast, temperature variability during the late Holocene was not accompanied by comparable vegetation changes. In particular, grass pollen (Poaceae) increased during periodic cold spells between 15,000 and 11,000 cal yr B.P., but a cold spell of similar magnitude ca. 2000 cal yr B.P. did not appear to affect vegetation. During the late Pleistocene, the isotopic record from the peat core shows variations similar to the D/H ratios in the Antarctic Taylor Dome ice core. However, the timing of the changes in the Harberton record is more in line with the timing of other Southern Hemisphere records.
Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl
