Assessing and Delineation of Groundwater Recharge Areas in Coastal Arid Area in Tunisia Using GIS, Remote Sensing Techniques and Self-organizing Map

In Gabès region (southeastern Tunisia), given the semi-arid to arid climate conditions, groundwater is an essential resource to supply the growth needs of the socio-economic development. To ensure sustainable development and preserve water resources, a careful estimation of the present day recharge amount and the delineation of the potential zones of rainfall precipitation are of required for an accurate evaluation of regional water balance. In this context, this study aims to a preliminary assessment of groundwater recharge in Gabes basin in regard to the delineation of the potential recharge areas of phreatic aquifers. Thus, a geological and hydrogeological collected database coupled with remote sensing techniques (RST) were used for the determination of the lateral variation of recharging zone ,Treatment by ArcGIS and Matlab softwares and Kohonen self-organizing maps (K-SOM) approaches.The obtained results indicate that five recharge potential areas have been identified and classified as 27% very low, 23% low, 40% moderate recharge, 7% good and 3 % very good potential recharge located principally on southern part of the study region .This distribution is controlled principally by the geomorphological, geologic, and hydrogeologic features of the region . Reasonable management strategies based on a perennial exploitation of these low renewable resources are required to optimize the water dependent socio-economic development. The estimated groundwater potential recharge of Gabès aquifer system using K-SOM and RST is of 11.4 Mm3.y-1. This recharging rate is very low it present 7% of the total rain, thus it must be ameliorated. K-SOM and RST approach is a useful method for groundwater potential recharge mapping and is a helpful of wells establishment and groundwater sustainable management.an isotopic analyses is recommended to ameliorate the decision maker to establish the adequate strategy.

A fast, single column extraction chromatography method for the isolation of Neodymium from iron-rich materials prior to radiogenic isotope ratio measurements

A novel separation method is described for the separation of Nd from Fe-rich, silicate samples in view of isotopic analyses. The procedure is based on the synergistic enhancement of the...

Genetic Identification Of Ground Ice By Petrographic Method

The advantages and limitations of the petrography method and the relevance of its use for the study of natural ice are reviewed in the present work. The petrographic method of ground ice study is often used for solving paleogeographic issues. The petrofabric analysis of ground ice is not only useful for descriptive purposes but, like the study of cryostructures, helps to infer growth processes and conditions. Different types of natural ice have specific features that can help us to determine ice genesis. Surface ice, such as glacier ice is often presented by foliation formed by large crystals (50-60 mm); lake ice is characterised by the upper zone of small (6 mm x 3 mm) dendritic and equigranular crystals, which change with increasing depth to large (may exceed 200 mm) columnar and prismatic crystals; segregated ice is composed by crystals forming foliation. Ground ice, such as ice wedge is presented by vertical-band appearance and small crystals (2-2.5 mm); closed-cavity ice is often distinguished by radial-ray appearance produced by elongated ice crystals; injection ice is composed by anhedral crystals, showing the movement of water; snowbank ice is presented by a high concentration of circular bubbles and small (0.1-1 mm) equigranular crystals; icing is described by foliation and mostly columnar crystals. Identification of the origin of ground ice is a complicated task for geocryology because it is difficult to distinguish different types of ground ice based on only visual explorations. The simplest way to get an ice texture pattern is by using polarized light. Distinctions between genetic types of ground ice are not always made in studies, and that can produce erroneous inferences. Petrography studies of an ice object are helpful to clarify the data interpretation, e.g., of isotopic analyses. It is particularly relevant for heterogeneous ice wedges’ study.

Genesis of the Eastern Adamello Plutons (Northern Italy): Inferences for the Alpine Geodynamics

The Corno Alto–Monte Ospedale magmatic complex crops out at the eastern border of the Adamello batholith, west of the South Giudicarie Fault (NE Italy). This complex includes tonalites, trondhjemites, granodiorites, granites and diorites exhibiting an unfoliated structure suggesting passive intrusion under extensional-to-transtensional conditions. Major, minor elements, REE and isotopic analyses and geochemical and thermodynamic modelling have been performed to reconstruct the genesis of this complex. Geochemical analyses unravel a marked heterogeneity with a lack of intermediate terms. Samples from different crust sections were considered as possible contaminants of a parental melt, with the European crust of the Serre basement delivering the best fit. The results of the thermodynamic modelling show that crustal melts were produced in the lower crust. Results of the geochemical modelling display how Corno Alto felsic rocks are not reproduced by fractional crystallization nor by partial melting alone: their compositions are intermediate between anatectic melts and melts produced by fractional crystallization. The tectonic scenario which favored the intrusion of this complex was characterized by extensional faults, active in the Southalpine domain during Eocene. This extensional scenario is related to the subduction of the Alpine Tethys in the Eastern Alps starting at Late Cretaceous time.

Who’s been using my burial mound? Radiocarbon dating and isotopic tracing of human diet and mobility at the collective burial site, Le Tumulus des Sables, southwest France

The burial mound of Le Tumulus des Sables, southwest France, contains archaeological artefacts spanning from the Neolithic to the Iron Age. Human remains have been found throughout the burial mound, however their highly fragmented state complicates the association between the burial mound structure and the archaeological material. Radiocarbon dating and isotopic analyses of human teeth have been used to investigate the chronology, diet and mobility of the occupants. Radiocarbon dating shows that the site was used for burials from the Neolithic to Iron Age, consistent with the range of archaeological artefacts recovered. δ13C and δ15N values (from dentine collagen) suggest a predominately terrestrial diet for the population, unchanging through time. 87Sr/86Sr (on enamel and dentine) and δ18O (on enamel) values are consistent with occupation of the surrounding region, with one individual having a δ18O value consistent with a childhood spent elsewhere, in a colder climate region. These results showcase the complex reuse of this burial mound by a mostly local population over a period of about 2000 years.

Organic matter characteristics of a rapidly eroding permafrost cliff in NE Siberia (Lena Delta, Laptev Sea region)

Organic carbon (OC) stored in Arctic permafrost represents one of Earth’s largest and most vulnerable terrestrial carbon pools. Amplified climate warming across the Arctic results in widespread permafrost thaw. Permafrost deposits exposed at river cliffs and coasts are particularly susceptible to thawing processes. Accelerating erosion of terrestrial permafrost along shorelines leads to increased transfer of organic matter (OM) to nearshore waters. However, the amount of terrestrial permafrost carbon and nitrogen as well as the OM quality in these deposits are still poorly quantified. Here, we characterise the sources and the quality of OM supplied to the Lena River at a rapidly eroding permafrost river shoreline cliff in the eastern part of the delta (Sobo-Sise Island). Our multi-proxy approach captures bulk elemental, molecular geochemical and carbon isotopic analyses of late Pleistocene Yedoma permafrost and Holocene cover deposits, discontinuously spanning the last ~52 ka. We show that the ancient permafrost exposed in the Sobo-Sise cliff has a high organic carbon content (mean of about 5 wt%).We found that the OM quality, which we define as the intrinsic potential to further transformation, decomposition, and mineralization, is also high as inferred by the lipid biomarker inventory. The oldest sediments stem from Marine Isotope Stage (MIS) 3 interstadial deposits (dated to 52 to 28 cal kyr BP) and is overlaid by Last Glacial MIS 2 (dated to 28 to 15 cal ka BP) and Holocene MIS 1 (dated to 7–0 cal ka BP) deposits. The relatively high average chain length (ACL) index of n-alkanes along the cliff profile indicates a predominant contribution of vascular plants to the OM composition. The elevated ratio of iso and anteiso-branched FAs relative to long chain (C ≥ 20) n-FAs in the interstadial MIS 3 and the interglacial MIS 1 deposits, suggests stronger microbial activity and consequently higher input of bacterial biomass during these climatically warmer periods. The overall high carbon preference index (CPI) and higher plant fatty acid (HPFA) values as well as high C / N ratios point to a good quality of the preserved OM and thus to a high potential of the OM for decomposition upon thaw. A decrease of HPFA values downwards along the profile probably indicates a relatively stronger OM decomposition in the oldest (MIS 3) deposits of the cliff. The characterisation of OM from eroding permafrost leads to a better assessment of the greenhouse gas potential of the OC released into river and nearshore waters in future, which is important to understand the consequences of a warming climate in Arctic environments on the global carbon cycle.

Emerging Ecotone and Microbial Community of a Sulfidic Spring in the Reka River Near Škocjanske Jame, Slovenia

During long periods with no precipitation, a sulfidic spring (Smrdljivec) appears in the dry bed of the Reka River before sinking into the karst underground. The study characterizes the area’s geological setting, development of microbial communities and an ecotone, and impact on the vulnerable karst ecosystem. Geological mapping of the area, stable isotopic analyses, field measurements, and physico-chemical and toxicity analyses were applied to elucidate the environmental conditions. The spring’s microbial diversity was assessed using cultivation methods, microscopy, and metagenomics. Sulfur compounds in the spring probably originate from coal layers in the vicinity. Metagenomic analyses revealed 175 distinct operational taxonomic units in spring water and biofilms. Proteobacteria predominated in developed biofilms, and a “core” microbiome was represented by methylotrophs, including Methylobacter, Methylomonas, and Methylotenera. Diatoms represented an important component of biofilm biomass. A combination of environmental factors and climatic conditions allows the formation and accessibility of emerging biodiversity hotspots and ecotones. Details of their dynamic nature, global impact, and distribution should be highlighted further and given more protection.

In situ oxygen isotope micro-analysis of faunal material and human teeth using a SHRIMP II: a new tool for palaeo-ecology and archaeology

A Sensitive High Resolution Ion MicroProbe (SHRIMP II) has been used to make high spatial resolution in situ micro-analyses of oxygen isotopes in fish otoliths, and teeth from fossil herbivores and a Neanderthal. Large intra-tooth variations in the oxygen isotopic composition (up to 9&) were observed in the enamel of herbivores from the Neanderthal fossil site of Payre, consistent with preservation of seasonal cyclicity. The range of isotopic compositions observed in Neanderthal tooth enamel was much smaller (w3&), possibly the result of a longer enamel maturation time averaging out variability. An archaeological otolith from a Preceramic site in Northern Peru exhibited marked changes in δ18O over life, due either to the fish occasionally migrating from the sea to a lower salinity habitat, or to short-lived rises in sea water temperature. A fish otolith from Australia’s Willandra Lakes World Heritage Area showed clear seasonal variations, but also a general trend towards isotopically heavier and more saline water, as indicated by higher δ18O and Sr/Ca values resulting from increased evaporation. The results of these case studies are compared to results of oxygen isotope analysis using more conventional methods and demonstrate the ability of the SHRIMP II to provide precise high spatial resolution in-situ oxygen isotope analyses of a variety of biogenic materials. This approach has major advantages over conventional methods. It can provide rapid, micro-scale isotopic analyses of sub-permil precision without the need for chemical preparation of the sample.