scholarly journals Comparison between Gas-adsorption Method and Liquid Phase-adsorption Method for the Surface Area Determination of Powders.

1957 ◽  
Vol 78 (8) ◽  
pp. 1151-1154 ◽  
Author(s):  
Kunio Tamaki
2015 ◽  
Vol 5 (1) ◽  
pp. 152-159
Author(s):  
Иванов ◽  
Evgeniy Ivanov ◽  
Мельников ◽  
Dmitriy Melnikov ◽  
Голышкин ◽  
...  

Obtaining valuable components of fuels and petrochemical products from vegetable raw materials is complicated by its complex structure. To reduce energy consumption and increase the yield of desired products biomass pretreatment is used, during which partial removal of lignin and hemicellulose takes place. The use of irradiation causes destruction of intermolecular and intramolecular bonds within the structure of the lignocellulosic materials, which leads to decrease in the degree of crystallinity and increase of available surface area. Pretreatment with ionic liquids facilitates separation of lignin and hemicellulose from cellulose which dissolves and acquires amorphous structure. The resulting substrate has high available surface area, but it loses quality upon drying. Determination of the degree of crystallinity by X-ray diffraction and the available surface area and pore size by the adsorption method using an indicator of the effectiveness of the pretreatment is conducted. The use of gas adsorption methods requires drying the samples, which negates the results of many kinds of preprocessing. The use of liquid-phase adsorption methods based on the comparison of the concentration of substances in the feed solution, and after equilibrium with the surface of the substrate are established, can more accurately determine the available surface area and pores size. Application of liquid phase method does not require any preparation of samples prior to analysis, in contrast to the gas adsorption method. When comparing the results of analysis by gas adsorption BET of liquid phase adsorption of glucose on the surface of the samples of the lignocellulosic raw material it has been found that after ionic liquids pretreatment available surface area has increased by 300-400 %, and the pore volume increased by 450-1700 %.


2009 ◽  
Vol 15 (S2) ◽  
pp. 324-325
Author(s):  
M Lundberg ◽  
P Stanley Jørgensen ◽  
JR Bowen ◽  
Å Persson ◽  
AK Srivastava ◽  
...  

Extended abstract of a paper presented at Microscopy and Microanalysis 2009 in Richmond, Virginia, USA, July 26 – July 30, 2009


HortScience ◽  
2000 ◽  
Vol 35 (3) ◽  
pp. 426C-426
Author(s):  
M.K. Upadhyaya ◽  
N.H. Furness

Surface area of cucumbers, carrots, parsnips, and beets was determined using the following non-destructive methods: Baugerod's method, Baugerod's method with inclusion of a factor correcting for substitution of weight for volume in the formula, and a novel image analysis method. Accuracy of the methods was ascertained by comparison with a direct shrink-wrap replica method of surface area measurement. Vegetables ranged in shape from cylindrical (cucumber and carrot) to conical (parsnip and beet). No difference in accuracy among methods of surface area determination was detected for carrots or beets. Baugerod's method and the image analysis technique differed significantly from the direct shrink-wrap replica technique for surface area determination of parsnips and cucumbers, respectively. Inclusion of a correction factor in Baugerod's method did not increase the accuracy of this method for any of the vegetables. The precision and repeatability of each method was determined by repeated measures analysis. Baugerod's method lost precision and repeatability for the conically shaped vegetables. Conversely, the shrink-wrap replica method lost precision and repeatability for the cylindrically shaped vegetables. The image analysis technique was precise and highly repeatable over the range of vegetable shapes. The development of a rapid, accurate, and precise non-destructive method of surface area measurement using image analysis techniques will provide a useful tool in the physiological study of vegetable products. Applicability of such a method over a range of vegetable shapes will be of additional value.


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