scholarly journals Vinyl Polymerization. CCCXCVIII. Radical Polymerization of Methyl Methacrylate Initiated with the System of Poly(β-alanine) or α-Amylase and Cu(II) Ion in the Aqueous Solution of Urea

1981 ◽  
Vol 13 (1) ◽  
pp. 7-12 ◽  
Author(s):  
Tatsuro Ouchi ◽  
Akira Kuriyama ◽  
Minoru Imoto
2016 ◽  
Vol 12 ◽  
pp. 2378-2389 ◽  
Author(s):  
Judita Britner ◽  
Helmut Ritter

The first detailed study on free-radical polymerization, copolymerization and controlled radical polymerization of the cyclic push–pull-type monomer methylenelactide in comparison to the non-cyclic monomer α-acetoxyacrylate is described. The experimental results revealed that methylenelactide undergoes a self-initiated polymerization. The copolymerization parameters of methylenelactide and styrene as well as methyl methacrylate were determined. To predict the copolymerization behavior with other classes of monomers, Q and e values were calculated. Further, reversible addition fragmentation chain transfer (RAFT)-controlled homopolymerization of methylenelactide and copolymerization with N,N-dimethylacrylamide was performed at 70 °C in 1,4-dioxane using AIBN as initiator and 2-(((ethylthio)carbonothioyl)thio)-2-methylpropanoic acid as a transfer agent.


1981 ◽  
Vol 13 (2) ◽  
pp. 105-109 ◽  
Author(s):  
Minoru Imoto ◽  
Tatsuro Ouchi ◽  
Masaya Inaba ◽  
Tai Tokuyama ◽  
Hitoshi Obata ◽  
...  

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