The mixed alkali effect in the MgO–Li2O–Na2O–K2O–B2O3 glass system

Author(s):  
Abdul Hameed ◽  
◽  
Md. Shareefuddin ◽  
M. Narasimha M. Narasimha Chary ◽  
2013 ◽  
Vol 22 ◽  
pp. 278-283
Author(s):  
A. EDUKONDALU ◽  
M. A. SAMEE ◽  
SHAIKH KAREEM AHMMAD ◽  
SAIR MD. TAQIULLAH ◽  
SYED RAHMAN ◽  
...  

Mixed alkali tungsten borate glasses xLi2O–(30–x) K2O–10WO3–60B2O3 (0 < x < 30) were prepared from the melts. These glasses were characterized using X-ray diffraction, differential scanning calorimetry and density measurements. Optical absorption studies were carried out as a function of alkali content to look for mixed alkali effect (MAE) on the spectral properties of these glasses. From the study of ultraviolet absorption edge, the optical band gap energies and Urbach energies were evaluated. The average electronic polarizability of the oxide ion, optical basicity and the interaction parameters were also evaluated for all the glasses. Many of these parameters vary non-linearly exhibiting a minima or maxima with increasing alkali concentration, indicating the mixed alkali effect. An attempt is made to interpret MAE in this glass system in terms of its glass structure.


2020 ◽  
Vol 548 ◽  
pp. 120314
Author(s):  
Zhitao Shan ◽  
Yanfei Zhang ◽  
Shujiang Liu ◽  
Haizheng Tao ◽  
Yuanzheng Yue

2004 ◽  
Vol 58 (5) ◽  
pp. 694-698 ◽  
Author(s):  
A Agarwal ◽  
V.P Seth ◽  
S Sanghi ◽  
P Gahlot ◽  
S Khasa

2020 ◽  
Vol 11 (3) ◽  
pp. 396-414
Author(s):  
Courtney Calahoo ◽  
Yang Xia ◽  
Ru Zhou

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