Organic Geochemistry in Relation to the Depositional Environments of Middle Jurassic Coal Seams, Danish Central Graben, and Implications for Hydrocarbon Generative Potential

Author(s):  
Henrik Ingermann Petersen, Per Rose
2020 ◽  
Vol 70 (1) ◽  
pp. 87-102
Author(s):  
Rzger A. Abdula ◽  

A collection of 165 crude oils, 12 oil seeps, and 24 extracts and recovered samples from 25 oil exploratory wells and 6 oil seeps in the Southern Mesopotamian Basin were studied. Biomarker configurations and other organic geochemistry parameters were used to discover the depositional environments and to classify the oil samples as provenance groups. Petroleum liquids were geochemically classified into four groups. The first group of oils, Middle Jurassic Zagros Fold Belt, is located in the Maysan, Basra, and Thi qar provinces of the basin that has pristane/phytane (Pr/Ph) proportions ≤0.97 and contains sufficient gammacerane. Methylphenanthrene index 1 (MPI 1) values show that the first group of oils is mature. Oils from Group 2, Upper Jurassic–Lower Cretaceous Sulaiy/Yamama, by disparity have Pr/Ph proportions between 0.72 and 1.12 and relatively moderate C28/C29 steranes, 0.52-0.88. Ts/Tm ratios indicate thermal maturity for Group 2 oils. Unlike oils from other groups, the oils from Group 3, Cretaceous to Tertiary oils, in Subba Field hold the highest canonical variable (CV) values that range between 0.43 and –2.30. The fourth group, Late Triassic-Middle Jurassic oil seeps, is the oldest among all groups. This group holds an average carbon isotope ratio –28.25‰ and –28.10‰ for saturates and aromatics respectively, which are the lowest values among all oils in the studied region. The Tithonian-Berriasian Sulaiy/Yamama oils further divided into three subgroups. The first subgroup, A, has carbon preference index (CPI) values of ≤1.08 (average 0.86) and C28/C29 sterane of 0.56-1.13 with an average of 0.65. Second subgroup, B, holds CPI ≤1.18 (average 0.99) and C28/C29 sterane 0.55-0.82 with an average of 0.63. The last subgroup, C, has CPI values ≤0.93 (average 0.85) and high C27 and C29 steranes (average 46.5% and 39.61%, respectively). In the same way, the Group 3 can be further subdivided into two subgroups based on values of carbon isotopes for saturates and aromatics. The oils from this group are heterogeneous and can be further divided into Tertiary Subgroup and Cretaceous Subgroup.


Author(s):  
Henrik I. Petersen ◽  
Jan Andsbjerg ◽  
Jørgen A. Bojesen-Koefoed ◽  
Hans P. Nytoft ◽  
Per Rosenberg

NOTE: This monograph was published in a former series of GEUS Bulletin. Please use the original series name when citing this monograph. For example: Petersen, H. I., Andsbjerg, J., Bojesen-Koefoed, J. A., Nytoft, H. P., & Rosenberg, P. (1998). Petroleum potential and depositional environments of Middle Jurassic coals and non-marine deposits, Danish Central Graben, with special reference to the Søgne Basin. Geology of Denmark Survey Bulletin, 36, 1-80. https://doi.org/10.34194/dgub.v36.5022 _______________ New data from five wells in the Søgne Basin, Danish Central Graben of the North Sea - West Lulu-1, West Lulu-3, Lulu-1, Amalie-1 and Cleo-1 - together with previously released data from the West Lulu-2 well, show that the cumulative thickness of the Bryne Formation coal seams decreases towards the palaeo-shoreline from 5.05 m to 0.60 m, and that the seams have varying extents. Their overall organic petrographic and geochemical composition reflects the palaeoenvironmental conditions in the precursor mires, in particular the rate of rise in the water table, principally related to the relative rise in sea level, and the degree of marine influence. Laterally towards the palaeo-shoreline, all coal seams have increased proportions of C27 steranes and higher C35-homohopane indices suggesting stronger marine influence on the coastal reaches of the ancient mires. In each well it is also observed that coal seams formed during accelerated relative sea-level rise (T-seams) are characterised by higher contents of sterane C27 and higher C35-homohopane indices than seams formed during slower rates of base-level rise (R-seams). The most landward and freshwater-influenced parts of the seams have higher proportions of sterane C29 and the highest Pr/Ph ratios. The coals, with respect to thermal maturity, are well within the oil window, except in the Amalie-1 well where they are more mature. The largest average hydrogen indices and thermally extracted and generated bitumen yields are obtained from the T-seams. However, generally an increase in the hydrogen index is recorded in a seaward direction for all seams. Multivariate regression analysis demonstrates that collotelinite, telinite, the vitrinite maceral group, vitrinite-rich microlithotypes and the TOC content have a significant positive influence on the remaining generative potential represented by S2. Pyrolysis-gas chromatography reveals that during maturation the coals will generate from 72.4 to 82.0% oil-like components and only 18.0 to 27.6% gas. However, this does not necessarily imply that all of these oil-like components can be expelled to form a crude oil accumulation. Distribution of C27–29 regular steranes shows good correlation between extracts of Bryne Formation coals and oils/condensates present in Bryne Formation sandstones. The sum of evidence indicates that the coals in the Søgne Basin have generated and are still capable of generating liquid and gaseous petroleum, but with respect to petroleum generation potential, they are not as good as the documented oil-prone Middle Jurassic coals from North-East Greenland and Tertiary coals from Asia. Mudstones intercalated with the Bryne Formation coals have a similar or lower generative potential as the coals. In areas outside the Søgne Basin, the coastal plain deposits of the Central Graben Group contain predominantly terrestrial-derived kerogen type III or IIb. The thermal maturity of the organic matter ranges from close to or within the peak oil generation range in the oil window (Alma-1x, Anne-3a and M-8 well) to the late oil window (Elly-3 and Falk-1 wells) or close to the end of the oil window (Skjold Flank-1 well). Only a limited generative potential remains in Elly-3, but the kerogen may initially have possessed a good petroleum potential. In the Falk-1 well, a good generative capacity still remains. The kerogen in Skjold Flank-1 may possess the capability to generate condensate and gas, whereas the organic matter in the Alma-1x, Anne-3a and M-8 wells generally exhibits a poor petroleum generative potential.  


1994 ◽  
Vol 33 ◽  
pp. 1-55
Author(s):  
Henrik Ingermann Petersen

Five cored wells located in the Fennoscandian Border Zone in the Øresund area, Denmark, encountered Lower or Middle Jurassic coal-bearing strata; the coal seams are Lignite to Sub-bituminous A/High Vol. Bituminous C in rank. A number of shallowing-upward units are recognized in the five wells. Each unit is capped by a coal seam. Correlation of these shallowing-upward units between wells is difficult on the basis of available biostratigraphy and log data. Seven of the coal seams result from establishment of peatforming conditions due to infilling of freshwater lakes, whereas the last two of the coal seams result from peat accumulation on top of restricted brackish lagoon or bay sediments. However, only one of the latter two seams accumulated in an environment influenced by saline water. Hence, the investigated coals represent almost entirely freshwater peat-forming environments. Three main types of environments are defined: 1) Type 1 is a sparsely vegetated open water swamp; it is represented by a limnic facies. The deposit is typically a carbonaceous claystone with a high content of allochthonous organic matter; 2) Type 2 is a densely vegetated rheotrophic, nutrient-rich and anoxic swamp; it is represented by a limnotelmatic to telmatic facies. The coal has a very high content of humified organic matter; 3) Type 3, subdivided into the types 3a and 3b, is the driest environment of the three types. Type 3a is a desiccated ombrotrophic raised bog represented by a terrestrial facies. It is strongly influenced by a fluctuating watertable. The coals contain a high content of inertinite that generally shows a low reflectance. Type 3b is a mesotrophic to ombrotrophic domed bog; the environment alternates between dry oxidizing conditions and wet conditions. It is represented by a telmatic to terrestrial facies. In general, the three types of environments form ecosystems characterized by the groundwater influence, nutrient supply, and vegetation. Successions representing the hydrological evolution towards drier conditions due to vertical peat accretion are recognized in some of the seams. The vegetation was small-statured and consisted of a prominent herbaceous type of flora, shrub-like plants, smaller arboreous plants and, to a lesser extent, larger plants.


2013 ◽  
Vol 734-737 ◽  
pp. 156-160
Author(s):  
Meng Li ◽  
Zheng Fei Zhang ◽  
Sheng Zhang ◽  
Ming Ming Wang ◽  
Xiang Dong Gao ◽  
...  

Field-based lithofacies in the Middle Jurassic coal measures of the Juhugeng coal mine area of Qinghai Province have been identified employing lithology, geometry and lateral facies relationships. The coal measures were deposited in a range of environments spanning from braided river, delta to lake, and economic coal seams have been formed in the deltaic interdistributary bay and fluvial flood basin environments. The coal has a rank ranging from gas coal to coking coal, and the vitrinite macerals have a relatively high content, being from 60%~80%. Cleats and fractures of coal reservoirs are well developed. The isothermal adsorption experiments reveal that coal in the Juhugeng mine has relatively low Langmuir volume and relatively high Langmuir pressure with low to medium absorbability. All these conditions are beneficial to the formation and preservation of the coalbed methane.


2007 ◽  
Vol 22 (11) ◽  
pp. 2456-2485 ◽  
Author(s):  
Leszek Marynowski ◽  
Michał Zatoń ◽  
Bernd R.T. Simoneit ◽  
Angelika Otto ◽  
Mariusz O. Jędrysek ◽  
...  

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