Electron number density conservation model combined with a self-absorption correction methodology for analysis of nanostructure plasma using laser-induced breakdown spectroscopy

2020 ◽  
Vol 59 (8) ◽  
pp. 2559
Author(s):  
Zahid Farooq ◽  
Raheel Ali ◽  
Aqrab ul Ahmad ◽  
M. Yaseen ◽  
Mian H. R. Mahmood ◽  
...  
2017 ◽  
Vol 35 (2) ◽  
pp. 313-325 ◽  
Author(s):  
A. Hayat ◽  
S. Bashir ◽  
M. S. Rafique ◽  
R. Ahmed ◽  
M. Akram ◽  
...  

AbstractSpatial confinement effects on plasma parameters and surface morphology of laser-ablated Mg are studied by introducing a metallic blocker as well as argon (Ar) gas at different pressures. Nd: YAG laser at various fluences ranging from 7 to 28 J/cm2 was employed to generate Mg plasma. Confinement effects offered by metallic blocker are investigated by placing the blocker at different distances of 6, 8, and 10 mm from the target surface; whereas spatial confinement offered by environmental gas is explored under four different pressures of 5, 10, 20, and 50 Torr. Laser-induced breakdown spectroscopy analysis revealed that both plasma parameters, that is, excitation temperature and electron number density initially are strongly dependent upon both pressures of environmental gases and distances of blockers. The maximum electron temperature of Mg plasma is achieved at Ar gas pressure of 20 Torr, whereas maximum electron number density is achieved at 50 Torr. It is also observed that spatial confinement offered by metallic blocker is responsible for the significant enhancement of both electron temperature and electron number density of Mg plasma. Maximum values of electron temperature and electron number density without blocker are 8335 K and 2.4 × 1016 cm−3, respectively, whereas these values are enhanced to 12,200 K and 4 × 1016 cm−3 in the presence of blocker. Physical mechanisms responsible for the enhancement of Mg plasma parameters are plasma compression, confinement and pronounced collisional excitations due to reflection of shock waves. Scanning electron microscope analysis was performed to explore the surface morphology of laser-ablated Mg. It reveals the formation of ripples and channels that become more distinct in the presence of blocker due to plasma confinement. The optimum combination of blocker distance, fluence and Ar pressure can identify the suitable conditions for defining the role of plasma parameters for surface structuring.


2017 ◽  
Vol 35 (1) ◽  
pp. 159-169 ◽  
Author(s):  
H. Iftikhar ◽  
S. Bashir ◽  
A. Dawood ◽  
M. Akram ◽  
A. Hayat ◽  
...  

AbstractThe effect of the transverse magnetic field on laser-induced breakdown spectroscopy and surface modifications of germanium (Ge) has been investigated at various fluences. Ge targets were exposed to Nd: YAG laser pulses (1064 nm, 10 ns, 1 Hz) at different fluences ranging from 3 to 25.6 J/cm2 to generate Ge plasma under argon environment at a pressure of 50 Torr. The magnetic field of strength 0.45 Tesla perpendicular to the direction of plasma expansion was employed by using two permanent magnets. The emission spectra of laser-induced Ge plasma was detected by the laser-induced breakdown spectroscopy system. The electron temperature and number density of Ge plasma are evaluated by using the Boltzmann plot and stark broadening methods, respectively. The variations in emission intensity, electron temperature (Te), and number density (ne) of Germanium plasma are explored at various fluences, with and without employment of the magnetic field. It is observed that the magnetic field is responsible for significant enhancement of both excitation temperature and number density at all fluences. It is revealed that an excitation temperature increases from Te,max,without B = 16,190 to Te,max,with B = 20,123 K. Similarly, the two times enhancement in the electron density is observed from ne,max,without B = 2 × 1018 to ne,max,with B = 4 × 1018 cm−3. The overall enhancement in Ge plasma parameters in the presence of the magnetic field is attributed to the Joule heating effect and adiabatic compression. With increasing fluence both plasma parameters increase and achieve their maxima at a fluence of 12.8 J/cm2 and then decrease. In order to correlate the plasma parameters with surface modification, scanning electron microscope analysis of irradiated Ge was performed. Droplets and cones are formed for both cases. However, the growth of ridges and distinctness of features is more pronounced in case of the absence of the magnetic field; whereas surface structures become more diffusive in the presence of the magnetic field.


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